Characterization of vanadium in oil sands fluid petroleum coke using electron microscopy

Jocelyn E. Zuliani, Tomohiro Miyata, Teruyasu Mizoguchi, Jing Feng, Donald W. Kirk, Charles Q. Jia

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Naturally occurring vanadium is found in many heavy oils and bitumen, which are upgraded to synthetic crude oil via the coking process. During coking the vanadium concentrates in the solid heavy oil product, petroleum coke. However, potential releases of this toxic vanadium, either due to long term natural leaching from stockpiles or during combustion, presents environmental and health concerns. In this study, the vanadium present in petroleum coke was characterized using high resolution transmission electron microscope imaging with energy-dispersive X-ray spectroscopy. Vanadium was observed in nanocrystalline mineral clusters, and is consistently associated with silicon, oxygen, sulfur, and iron. A distinct lattice structure is observed in these nanocrystals. This result is different from previous theories, which predicted that the coking process did not decompose the vanadyl porphyrins present in bitumen. By identifying the vanadium nanocrystals in petroleum coke, the long term fate of vanadium in petroleum coke stockpiles in reclaimed land may be predicted.

Original languageEnglish
Pages (from-to)124-128
Number of pages5
JournalFuel
Volume178
DOIs
Publication statusPublished - 2016 Aug 15
Externally publishedYes

Keywords

  • Extraction process
  • Inorganic minerals
  • Long-term leachability
  • Oil sands petroleum coke
  • Vanadium nanocrystals
  • Vanadyl porphyrins

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Organic Chemistry

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