Characterization of nanocomposite polymer electrolyte based on P(ECH-EO)

H. Nithya, S. Selvasekarapandian, P. Christopher Selvin, D. Arun Kumar, M. Hema, D. Prakash

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

ZrO2 nanoparticles have been prepared by poly acrylamide gel route. The synthesized nanosized ZrO2 have been incorporated into plasticized polymer electrolyte (PPE), P(ECH-EO): LiClO4: γ-BL system to understand the effect of ZrO2 on the ionic conductivity. The X-ray diffraction pattern of the synthesized ZrO2 nanoparticles reveals the crystalline phase. The X-ray diffraction patterns of P(ECH-EO) based NCPEM confirm the polymersalt-nanoparticle complexation. The scanning electron microscope image of NCPEM confirms that the ZrO2 nanoparticles were distributed uniformly in the polymer matrix. The presence of nano filler has increased the ionic conductivity and the maximum dc conductivity value is found to be 6.24×10-6 S cm-1 at 303 K for 96(PPE): 4ZrO2 (mol%).

Original languageEnglish
Pages (from-to)3367-3373
Number of pages7
JournalPhysica B: Condensed Matter
Volume406
Issue number18
DOIs
Publication statusPublished - 2011 Sep 15
Externally publishedYes

Keywords

  • Differential scanning calorimetry
  • Electrical properties
  • P(ECH-EO)
  • ZrO

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

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