Abstract
Development of analytical methods sensitive to interfaces is an essential requirement to elucidate specific behaviors of molecules at liquid-solid and liquid-liquid interfaces. A resonant second harmonic generation spectroscopy is newly developed and applied to analysis of molecules at interfaces. Analysis by electrochemical STM and time-resolved total internal reflection fluorescence spectroscopy is also described. Complexation reactoins and molecular recognitions at liquid-liquid interfaces are analyzed by measurements of surface tension and ion transfer polarogram, and unusual selectiveity is achieved using suitable host molecules.
| Original language | English |
|---|---|
| Pages (from-to) | 1063-1075 |
| Number of pages | 13 |
| Journal | Bunseki Kagaku |
| Volume | 48 |
| Issue number | 12 |
| Publication status | Published - 1999 |
Keywords
- Ion transfer polarogram
- Liquid-liquid and solid-liquid interfaces
- Scanning tunnel microscope (STM)
- Surface second harmonic generation (SHG)
- Surface tension
- Time-resolved total internal reflection fluorescence spectroscopv
ASJC Scopus subject areas
- Analytical Chemistry