Abstract
Development of analytical methods sensitive to interfaces is an essential requirement to elucidate specific behaviors of molecules at liquid-solid and liquid-liquid interfaces. A resonant second harmonic generation spectroscopy is newly developed and applied to analysis of molecules at interfaces. Analysis by electrochemical STM and time-resolved total internal reflection fluorescence spectroscopy is also described. Complexation reactoins and molecular recognitions at liquid-liquid interfaces are analyzed by measurements of surface tension and ion transfer polarogram, and unusual selectiveity is achieved using suitable host molecules.
Original language | English |
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Pages (from-to) | 1063-1075 |
Number of pages | 13 |
Journal | Bunseki Kagaku |
Volume | 48 |
Issue number | 12 |
Publication status | Published - 1999 |
Keywords
- Ion transfer polarogram
- Liquid-liquid and solid-liquid interfaces
- Scanning tunnel microscope (STM)
- Surface second harmonic generation (SHG)
- Surface tension
- Time-resolved total internal reflection fluorescence spectroscopv
ASJC Scopus subject areas
- Analytical Chemistry