Characterization of molecules and molecular recognition at interfaces

Norio Teramae, Tatsuya Uchida, Akira Yamaguchi, Kimihisa Nochi, Tomohisa Yamashita, Takeshi Shioya

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Development of analytical methods sensitive to interfaces is an essential requirement to elucidate specific behaviors of molecules at liquid-solid and liquid-liquid interfaces. A resonant second harmonic generation spectroscopy is newly developed and applied to analysis of molecules at interfaces. Analysis by electrochemical STM and time-resolved total internal reflection fluorescence spectroscopy is also described. Complexation reactoins and molecular recognitions at liquid-liquid interfaces are analyzed by measurements of surface tension and ion transfer polarogram, and unusual selectiveity is achieved using suitable host molecules.

Original languageEnglish
Pages (from-to)1063-1075
Number of pages13
JournalBunseki Kagaku
Volume48
Issue number12
Publication statusPublished - 1999

Keywords

  • Ion transfer polarogram
  • Liquid-liquid and solid-liquid interfaces
  • Scanning tunnel microscope (STM)
  • Surface second harmonic generation (SHG)
  • Surface tension
  • Time-resolved total internal reflection fluorescence spectroscopv

ASJC Scopus subject areas

  • Analytical Chemistry

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