Ceria-catalyzed conversion of carbon dioxide into dimethyl carbonate with 2-cyanopyridine

Masayoshi Honda; Masazumi Tamura; Yoshinao Nakagawa; Satoru Sonehara; Kimihito Suzuki; Ken Ichiro Fujimoto; Keiichi Tomishige

doi:10.1002/cssc.201300229

Ceria-catalyzed conversion of carbon dioxide into dimethyl carbonate with 2-cyanopyridine

Masayoshi Honda, Masazumi Tamura, Yoshinao Nakagawa, Satoru Sonehara, Kimihito Suzuki, Ken Ichiro Fujimoto, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

117 Citations (Scopus)

Abstract

DMC run: Carbon dioxide can be converted into dimethyl carbonate in a reaction system involving 2-cyanopyridine as a dehydration agent, catalyzed by CeO₂. Regeneration of the coproduct 2-picolinamide can be achieved over a Na₂O/SiO₂ catalyst. As a whole, the system servest to react carbon dioxide with methanol to produce dimethyl carbonate.

Original language	English
Pages (from-to)	1341-1344
Number of pages	4
Journal	ChemSusChem
Volume	6
Issue number	8
DOIs	https://doi.org/10.1002/cssc.201300229
Publication status	Published - 2013 Aug

Keywords

carbon dioxide
carbonates
cerium
heterogeneous catalysis
metal oxides

ASJC Scopus subject areas

Environmental Chemistry
Chemical Engineering(all)
Materials Science(all)
Energy(all)

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10.1002/cssc.201300229

Cite this

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abstract = "DMC run: Carbon dioxide can be converted into dimethyl carbonate in a reaction system involving 2-cyanopyridine as a dehydration agent, catalyzed by CeO2. Regeneration of the coproduct 2-picolinamide can be achieved over a Na2O/SiO2 catalyst. As a whole, the system servest to react carbon dioxide with methanol to produce dimethyl carbonate.",

keywords = "carbon dioxide, carbonates, cerium, heterogeneous catalysis, metal oxides",

author = "Masayoshi Honda and Masazumi Tamura and Yoshinao Nakagawa and Satoru Sonehara and Kimihito Suzuki and Fujimoto, {Ken Ichiro} and Keiichi Tomishige",

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AU - Honda, Masayoshi

AU - Tamura, Masazumi

AU - Nakagawa, Yoshinao

AU - Sonehara, Satoru

AU - Suzuki, Kimihito

AU - Fujimoto, Ken Ichiro

AU - Tomishige, Keiichi

PY - 2013/8

Y1 - 2013/8

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AB - DMC run: Carbon dioxide can be converted into dimethyl carbonate in a reaction system involving 2-cyanopyridine as a dehydration agent, catalyzed by CeO2. Regeneration of the coproduct 2-picolinamide can be achieved over a Na2O/SiO2 catalyst. As a whole, the system servest to react carbon dioxide with methanol to produce dimethyl carbonate.

KW - carbon dioxide

KW - carbonates

KW - cerium

KW - heterogeneous catalysis

KW - metal oxides

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Ceria-catalyzed conversion of carbon dioxide into dimethyl carbonate with 2-cyanopyridine

Abstract

Keywords

ASJC Scopus subject areas

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