Abstract
CeO2 acted as an effective and reusable heterogeneous catalyst for the direct synthesis of 2-imidazolidinone from ethylenediamine carbamate (EDA-CA) without further addition of CO2 in the reaction system. 2-Propanol was the best solvent among the solvents tested from the viewpoint of selectivity to 2-imidazolidinone, and the use of an adequate amount of 2-propanol provided high conversion and selectivity for the reaction. This positive effect of 2-propanol on the catalytic reaction can be explained by the solubility of EDA-CA in 2-propanol under the reaction conditions and no formation of solvent-derived byproducts. This catalytic system using the combination of the CeO2 catalyst and the 2-propanol solvent provided 2-imidazolidinone in up to 83% yield on the EDA-CA basis at 413 K under Ar. The reaction conducted under Ar showed a higher reaction rate than that with pressured CO2, which clearly demonstrated the advantage of the catalytic system operated at low CO2 pressure or even without CO2.
Original language | English |
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Pages (from-to) | 27527-27535 |
Number of pages | 9 |
Journal | ACS Omega |
Volume | 6 |
Issue number | 41 |
DOIs | |
Publication status | Published - 2021 Oct 19 |
ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)