Cationic platinum-complex-catalyzed skeletal reorganization of enynes

Shuichi Oi, Issei Tsukamoto, Sotaro Miyano, Yoshio Inoue

Research output: Contribution to journalArticlepeer-review

133 Citations (Scopus)

Abstract

The skeletal reorganization of 1,6-enynes into 1-vinylcyclopentenes was catalyzed by a cationic platinum complex under extremely mild conditions. The unusual rearrangement of the carbon skeleton, involving the cleavage of both the double and triple carbon-carbon bonds, was observed in certain cases and confirmed by 13C- and 2H-labeling experiments. Reaction mechanisms describing the rearrangement of carbocations are proposed.

Original languageEnglish
Pages (from-to)3704-3709
Number of pages6
JournalOrganometallics
Volume20
Issue number17
DOIs
Publication statusPublished - 2001 Aug 20

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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