Abstract
The skeletal reorganization of 1,6-enynes into 1-vinylcyclopentenes was catalyzed by a cationic platinum complex under extremely mild conditions. The unusual rearrangement of the carbon skeleton, involving the cleavage of both the double and triple carbon-carbon bonds, was observed in certain cases and confirmed by 13C- and 2H-labeling experiments. Reaction mechanisms describing the rearrangement of carbocations are proposed.
Original language | English |
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Pages (from-to) | 3704-3709 |
Number of pages | 6 |
Journal | Organometallics |
Volume | 20 |
Issue number | 17 |
DOIs | |
Publication status | Published - 2001 Aug 20 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry