Cationic metallogermylene and dicationic dimetallodigermenes: Synthesis by chloride abstraction from N-heterocyclic carbene-stabilized chlorometallogermylenes

Koya Inomata, Takahito Watanabe, Hiromi Tobita

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

Reaction of NHC-stabilized dichlorogermylenes (NHC = N-heterocyclic carbene) with an anionic tungsten complex produced NHC-stabilized chlorometallogermylenes. Subsequent chloride abstraction from the products with NaBAr4 (Ar = 3,5-(CF3)2C6H3) gave a cationic metallogermylene or dicationic dimetallodigermenes.

Original languageEnglish
Pages (from-to)14341-14344
Number of pages4
JournalJournal of the American Chemical Society
Volume136
Issue number41
DOIs
Publication statusPublished - 2014 Oct 15

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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