Cationic metallogermylene and dicationic dimetallodigermenes: Synthesis by chloride abstraction from N-heterocyclic carbene-stabilized chlorometallogermylenes

Koya Inomata; Takahito Watanabe; Hiromi Tobita

doi:10.1021/ja506018f

Cationic metallogermylene and dicationic dimetallodigermenes: Synthesis by chloride abstraction from N-heterocyclic carbene-stabilized chlorometallogermylenes

Koya Inomata, Takahito Watanabe, Hiromi Tobita

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Reaction of NHC-stabilized dichlorogermylenes (NHC = N-heterocyclic carbene) with an anionic tungsten complex produced NHC-stabilized chlorometallogermylenes. Subsequent chloride abstraction from the products with NaBAr₄ (Ar = 3,5-(CF₃)₂C₆H₃) gave a cationic metallogermylene or dicationic dimetallodigermenes.

Original language	English
Pages (from-to)	14341-14344
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	41
DOIs	https://doi.org/10.1021/ja506018f
Publication status	Published - 2014 Oct 15

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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Cationic metallogermylene and dicationic dimetallodigermenes : Synthesis by chloride abstraction from N-heterocyclic carbene-stabilized chlorometallogermylenes. / Inomata, Koya; Watanabe, Takahito; Tobita, Hiromi.

In: Journal of the American Chemical Society, Vol. 136, No. 41, 15.10.2014, p. 14341-14344.

Research output: Contribution to journal › Article › peer-review

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abstract = "Reaction of NHC-stabilized dichlorogermylenes (NHC = N-heterocyclic carbene) with an anionic tungsten complex produced NHC-stabilized chlorometallogermylenes. Subsequent chloride abstraction from the products with NaBAr4 (Ar = 3,5-(CF3)2C6H3) gave a cationic metallogermylene or dicationic dimetallodigermenes.",

author = "Koya Inomata and Takahito Watanabe and Hiromi Tobita",

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N2 - Reaction of NHC-stabilized dichlorogermylenes (NHC = N-heterocyclic carbene) with an anionic tungsten complex produced NHC-stabilized chlorometallogermylenes. Subsequent chloride abstraction from the products with NaBAr4 (Ar = 3,5-(CF3)2C6H3) gave a cationic metallogermylene or dicationic dimetallodigermenes.

AB - Reaction of NHC-stabilized dichlorogermylenes (NHC = N-heterocyclic carbene) with an anionic tungsten complex produced NHC-stabilized chlorometallogermylenes. Subsequent chloride abstraction from the products with NaBAr4 (Ar = 3,5-(CF3)2C6H3) gave a cationic metallogermylene or dicationic dimetallodigermenes.

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Cationic metallogermylene and dicationic dimetallodigermenes: Synthesis by chloride abstraction from N-heterocyclic carbene-stabilized chlorometallogermylenes

Abstract

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