TY - JOUR
T1 - Cation Transport Through Liquid Membranes Mediated by Photoreactive Crown Ethers. Effects of Alkali Metal Cations on Their Photoreactivities and Transporting Properties
AU - Anzai, Jun‐Ichi ‐I
AU - Suzuki, Yasuhiro
AU - Ueno, Akihiko
AU - Osa, Tetsuo
PY - 1985
Y1 - 1985
N2 - Photoreactivities and cation transporting properties of monomeric, dimeric, and polymeric crown ethers which contain cinnamoyl residues were investigated. Photochemical cycloaddition reaction of the cinnamoyl moieties was accelerated by NaCl or KCl for the dimeric and polymeric derivatives but not for the monomeric one. The dimeric and polymeric crown ethers after irradiation in the presence of KCl showed a significant enhancement in the transport rates for Rb+ cation.
AB - Photoreactivities and cation transporting properties of monomeric, dimeric, and polymeric crown ethers which contain cinnamoyl residues were investigated. Photochemical cycloaddition reaction of the cinnamoyl moieties was accelerated by NaCl or KCl for the dimeric and polymeric derivatives but not for the monomeric one. The dimeric and polymeric crown ethers after irradiation in the presence of KCl showed a significant enhancement in the transport rates for Rb+ cation.
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U2 - 10.1002/ijch.198500069
DO - 10.1002/ijch.198500069
M3 - Article
AN - SCOPUS:84921147204
VL - 26
SP - 60
EP - 64
JO - Israel Journal of Chemistry
JF - Israel Journal of Chemistry
SN - 0021-2148
IS - 1
ER -