Catalytic oxidation of silyl enol ethers to 1,2-diketones employing nitroxyl radicals

Masaki Hayashi, Masatoshi Shibuya, Yoshiharu Iwabuchi

Research output: Contribution to journalReview articlepeer-review

23 Citations (Scopus)

Abstract

A novel and efficient method for the preparation of 1,2-diketones is reported. A series of -diketones were readily prepared by the nitroxyl-radical-catalyzed oxidation of silyl enol ethers using magnesium monoperoxyphthalate hexahydrate (MMPP6H) as the co-oxidant.

Original languageEnglish
Pages (from-to)1025-1030
Number of pages6
JournalSynlett
Volume23
Issue number7
DOIs
Publication statusPublished - 2012 Mar 30

Keywords

  • catalysis
  • diketones
  • enols
  • nitroxyl radical
  • oxidation

ASJC Scopus subject areas

  • Organic Chemistry

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