Catalytic and thermal hydrocarbonation of methyleneaziridines

Byoung Ho Oh, Itaru Nakamura, Yoshinori Yamamoto

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Reaction of the methyleneaziridine 1 with carbon pronucleophiles (2, H-CR3) proceeds smoothly in the presence of a palladium catalyst affording the corresponding hydrocarbonation products 5 in good to high yields. In the absence of palladium catalysts, the reaction of 1a with 2a at 120 °C afforded the ring opened product 9 in good yield.

Original languageEnglish
Pages (from-to)67-78
Number of pages12
JournalArkivoc
Volume2003
Issue number8
Publication statusPublished - 2003 Dec 1

Keywords

  • Hydrocarbonation
  • Methyleneaziridine
  • Palladium
  • Pronucleophile

ASJC Scopus subject areas

  • Organic Chemistry

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