Catalytic action of a single water molecule in a proton-migration reaction

Yoshiyuki Matsuda; Ayako Yamada; Ken Ichi Hanaue; Naohiko Mikami; Asuka Fujii

doi:10.1002/anie.201001364

Catalytic action of a single water molecule in a proton-migration reaction

Yoshiyuki Matsuda, Ayako Yamada, Ken Ichi Hanaue, Naohiko Mikami, Asuka Fujii

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

(Figure Presented) Baby steps: The mechanism of proton migration in an ionized acetone-water cluster was studied by IR spectroscopy. After the ionization, water abstracts a proton from the methyl group of the acetone moiety and transfers it to the carbonyl group (see picture).

Original language	English
Pages (from-to)	4898-4901
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	29
DOIs	https://doi.org/10.1002/anie.201001364
Publication status	Published - 2010 Jul 5

Keywords

Ion-molecule reactions
Ir spectroscopy
Proton migration
Reaction mechanisms
Water catalyst

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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title = "Catalytic action of a single water molecule in a proton-migration reaction",

abstract = "(Figure Presented) Baby steps: The mechanism of proton migration in an ionized acetone-water cluster was studied by IR spectroscopy. After the ionization, water abstracts a proton from the methyl group of the acetone moiety and transfers it to the carbonyl group (see picture).",

keywords = "Ion-molecule reactions, Ir spectroscopy, Proton migration, Reaction mechanisms, Water catalyst",

author = "Yoshiyuki Matsuda and Ayako Yamada and Hanaue, {Ken Ichi} and Naohiko Mikami and Asuka Fujii",

year = "2010",

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language = "English",

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T1 - Catalytic action of a single water molecule in a proton-migration reaction

AU - Matsuda, Yoshiyuki

AU - Yamada, Ayako

AU - Hanaue, Ken Ichi

AU - Mikami, Naohiko

AU - Fujii, Asuka

PY - 2010/7/5

Y1 - 2010/7/5

N2 - (Figure Presented) Baby steps: The mechanism of proton migration in an ionized acetone-water cluster was studied by IR spectroscopy. After the ionization, water abstracts a proton from the methyl group of the acetone moiety and transfers it to the carbonyl group (see picture).

AB - (Figure Presented) Baby steps: The mechanism of proton migration in an ionized acetone-water cluster was studied by IR spectroscopy. After the ionization, water abstracts a proton from the methyl group of the acetone moiety and transfers it to the carbonyl group (see picture).

KW - Ion-molecule reactions

KW - Ir spectroscopy

KW - Proton migration

KW - Reaction mechanisms

KW - Water catalyst

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DO - 10.1002/anie.201001364

M3 - Article

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JO - Angewandte Chemie - International Edition

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