Carbozincation of dipolar trimethylenemethane. A new route to functionalized organozinc reagents

Masaharu Nakamura, Naohiko Yoshikai, Eiichi Nakamura

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Dipolar trimethylenemethane species, thermally generated from 2,2-dialkoxy-1-methylenecyclopropane, reacts with a dialkylzinc reagent to generate an allylic zinc reagent, which then reacts in situ with a carbonyl compound to give a hydroxy acetal product as the result of coupling of the three reactants.

Original languageEnglish
Pages (from-to)146-147
Number of pages2
JournalChemistry Letters
Issue number2
DOIs
Publication statusPublished - 2002 Feb 5
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Carbozincation of dipolar trimethylenemethane. A new route to functionalized organozinc reagents'. Together they form a unique fingerprint.

Cite this