Carbozincation of dipolar trimethylenemethane. A new route to functionalized organozinc reagents

Masaharu Nakamura; Naohiko Yoshikai; Eiichi Nakamura

doi:10.1246/cl.2002.146

Carbozincation of dipolar trimethylenemethane. A new route to functionalized organozinc reagents

Masaharu Nakamura, Naohiko Yoshikai, Eiichi Nakamura

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Dipolar trimethylenemethane species, thermally generated from 2,2-dialkoxy-1-methylenecyclopropane, reacts with a dialkylzinc reagent to generate an allylic zinc reagent, which then reacts in situ with a carbonyl compound to give a hydroxy acetal product as the result of coupling of the three reactants.

Original language	English
Pages (from-to)	146-147
Number of pages	2
Journal	Chemistry Letters
Issue number	2
DOIs	https://doi.org/10.1246/cl.2002.146
Publication status	Published - 2002 Feb 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2002.146

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title = "Carbozincation of dipolar trimethylenemethane. A new route to functionalized organozinc reagents",

abstract = "Dipolar trimethylenemethane species, thermally generated from 2,2-dialkoxy-1-methylenecyclopropane, reacts with a dialkylzinc reagent to generate an allylic zinc reagent, which then reacts in situ with a carbonyl compound to give a hydroxy acetal product as the result of coupling of the three reactants.",

author = "Masaharu Nakamura and Naohiko Yoshikai and Eiichi Nakamura",

year = "2002",

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T1 - Carbozincation of dipolar trimethylenemethane. A new route to functionalized organozinc reagents

AU - Nakamura, Masaharu

AU - Yoshikai, Naohiko

AU - Nakamura, Eiichi

PY - 2002/2/5

Y1 - 2002/2/5

N2 - Dipolar trimethylenemethane species, thermally generated from 2,2-dialkoxy-1-methylenecyclopropane, reacts with a dialkylzinc reagent to generate an allylic zinc reagent, which then reacts in situ with a carbonyl compound to give a hydroxy acetal product as the result of coupling of the three reactants.

AB - Dipolar trimethylenemethane species, thermally generated from 2,2-dialkoxy-1-methylenecyclopropane, reacts with a dialkylzinc reagent to generate an allylic zinc reagent, which then reacts in situ with a carbonyl compound to give a hydroxy acetal product as the result of coupling of the three reactants.

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DO - 10.1246/cl.2002.146

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JF - Chemistry Letters

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Carbozincation of dipolar trimethylenemethane. A new route to functionalized organozinc reagents

Abstract

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