Carbonylation of tertiary propargylic alcohols catalyzed by a cationic palladium(II) complex: Synthesis of 2(5H)-Furanones

Koichi Matsushita; Tsunenori Komori; Shuichi Oi; Yoshio Inoue

doi:10.1016/S0040-4039(00)78211-6

Carbonylation of tertiary propargylic alcohols catalyzed by a cationic palladium(II) complex: Synthesis of 2(5H)-Furanones

Koichi Matsushita, Tsunenori Komori, Shuichi Oi, Yoshio Inoue

New Industry Creation Hatchery Center (NICHe)

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Tertiary propargylic alcohols reacted with carbon monoxide in the presence of catalytic quantities of a cationic palladium(II) complex, [Pd(CH₃CN)₂(PPh₃)₂](BF₄)₂, to afford 2(5H)-furanones and/or 2,3-dienoic acids, the precursor of the furanones, in good yields under mild conditions.

Original language	English
Pages (from-to)	5889-5890
Number of pages	2
Journal	Tetrahedron Letters
Volume	35
Issue number	32
DOIs	https://doi.org/10.1016/S0040-4039(00)78211-6
Publication status	Published - 1994 Aug 8

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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abstract = "Tertiary propargylic alcohols reacted with carbon monoxide in the presence of catalytic quantities of a cationic palladium(II) complex, [Pd(CH3CN)2(PPh3)2](BF4)2, to afford 2(5H)-furanones and/or 2,3-dienoic acids, the precursor of the furanones, in good yields under mild conditions.",

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AU - Komori, Tsunenori

AU - Oi, Shuichi

AU - Inoue, Yoshio

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N2 - Tertiary propargylic alcohols reacted with carbon monoxide in the presence of catalytic quantities of a cationic palladium(II) complex, [Pd(CH3CN)2(PPh3)2](BF4)2, to afford 2(5H)-furanones and/or 2,3-dienoic acids, the precursor of the furanones, in good yields under mild conditions.

AB - Tertiary propargylic alcohols reacted with carbon monoxide in the presence of catalytic quantities of a cationic palladium(II) complex, [Pd(CH3CN)2(PPh3)2](BF4)2, to afford 2(5H)-furanones and/or 2,3-dienoic acids, the precursor of the furanones, in good yields under mild conditions.

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