Carbonization of polyacrylonitrile in a two-dimensional space between montmorillonite lamellae

Naohiro Sonobe, Takashi Kyotani, Akira Tomita

    Research output: Contribution to journalArticlepeer-review

    69 Citations (Scopus)

    Abstract

    A novel method to prepare a new type of carbon from polyacrylonitrile (PAN) was developed by using the interlamellar opening of montmorillonite (MONT) as a two-dimensional space for carbonization. The complex of MONT with PAN was heat treated at 700°C to carbonize the intercalated PAN. The carbon produced was liberated from MONT by acid treatments. The carbon thus obtained looks like thin films under a scanning electron microscope and is considered to consist of planar macromolecules. Although it has a turbostratic structure at 700°C, it becomes a highly oriented graphite upon further heat treatment above 2500°C. An ordinary PAN was also prepared and heat treated for comparison.

    Original languageEnglish
    Pages (from-to)573-578
    Number of pages6
    JournalCarbon
    Volume26
    Issue number4
    DOIs
    Publication statusPublished - 1988

    Keywords

    • Carbonization
    • montmorillonite
    • polyacrylonitrile (PAN)
    • two-dimensional carbon

    ASJC Scopus subject areas

    • Chemistry(all)
    • Materials Science(all)

    Fingerprint

    Dive into the research topics of 'Carbonization of polyacrylonitrile in a two-dimensional space between montmorillonite lamellae'. Together they form a unique fingerprint.

    Cite this