Carbocupration of 1-alkynylphosphines followed by trapping with electrophiles

Shigenari Kanemura, Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

Treatment of 1-alkynylphosphine with magnesium dlalkylcuprate in ether results in regio- and stereosetective syn-csrbocupration. The alkenyicopper Intermediate reacts with electrophile, which leads to allylation, acylation, and phosphination. The phosphinatlon offers a new route to gem-diphosphinoaikene, an interesting phosphorus-based organic structure.

Original languageEnglish
Pages (from-to)2031-2033
Number of pages3
JournalOrganic letters
Volume9
Issue number10
DOIs
Publication statusPublished - 2007 May 10
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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