Canting angle dependence of single-chain magnet behaviour in chirality-introduced antiferromagnetic chains of acetate-bridged manganese(iii) salen-type complexes

Po Jung Huang, Hitoshi Miyasaka

Research output: Contribution to journalArticlepeer-review

Abstract

Canted antiferromagnetism (AFM) is considered an effective tool for designing single-chain magnets (SCMs) in homometallic chain systems. The family of manganese(iii) (MnIII) salen-type Schiff-base complexes is an outstanding building-unit candidate for designing SCMs because such complexes possess relatively large uniaxial magnetic anisotropy in the out-of-plane direction. However, SCM behaviour in simple alternating chains based on monomeric MnIII salen-type complexes has not been studied extensively. Herein, we report the SCM behaviour of canted AFM in an alternating chain of an acetate-bridged MnIII salen-type complex.

Original languageEnglish
Pages (from-to)16970-16978
Number of pages9
JournalDalton Transactions
Volume49
Issue number46
DOIs
Publication statusPublished - 2020 Dec 14

ASJC Scopus subject areas

  • Inorganic Chemistry

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