CaCu3Pt4O12: The first perovskite with the B site fully occupied by Pt4+

Ikuya Yamada; Yuka Takahashi; Kenya Ohgushi; Norimasa Nishiyama; Ryoji Takahashi; Kohei Wada; Takehiro Kunimoto; Hiroaki Ohfuji; Yohei Kojima; Toru Inoue; Tetsuo Irifune

doi:10.1021/ic100474x

CaCu₃Pt₄O₁₂: The first perovskite with the B site fully occupied by Pt⁴⁺

Ikuya Yamada, Yuka Takahashi, Kenya Ohgushi, Norimasa Nishiyama, Ryoji Takahashi, Kohei Wada, Takehiro Kunimoto, Hiroaki Ohfuji, Yohei Kojima, Toru Inoue, Tetsuo Irifune

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A novel A-site ordered perovskite CaCu₃Pt₄O ₁₂ was synthesized under high pressure and high temperature of 12 GPa and 1250 °C. CaCu₃Pt₄O₁₂ is the first perovskite in which the B site is fully occupied by Pt⁴⁺. The crystal structure refinement based on the synchrotron powder X-ray diffraction data shows that CaCu₃Pt₄O₁₂ crystallizes in the space group Im3(cubic) with a lattice constant of a = 7.48946(10) Å. The magnetic susceptibility data show the antiferromagnetic transition at T _N = 40 K, which is attributed to the magnetic ordering of Cu ²⁺ spins with S = ¹/₂.

Original language	English
Pages (from-to)	6778-6780
Number of pages	3
Journal	Inorganic chemistry
Volume	49
Issue number	15
DOIs	https://doi.org/10.1021/ic100474x
Publication status	Published - 2010 Aug 2
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic100474x

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title = "CaCu3Pt4O12: The first perovskite with the B site fully occupied by Pt4+",

abstract = "A novel A-site ordered perovskite CaCu3Pt4O 12 was synthesized under high pressure and high temperature of 12 GPa and 1250 °C. CaCu3Pt4O12 is the first perovskite in which the B site is fully occupied by Pt4+. The crystal structure refinement based on the synchrotron powder X-ray diffraction data shows that CaCu3Pt4O12 crystallizes in the space group Im3(cubic) with a lattice constant of a = 7.48946(10) {\AA}. The magnetic susceptibility data show the antiferromagnetic transition at T N = 40 K, which is attributed to the magnetic ordering of Cu 2+ spins with S = 1/2.",

author = "Ikuya Yamada and Yuka Takahashi and Kenya Ohgushi and Norimasa Nishiyama and Ryoji Takahashi and Kohei Wada and Takehiro Kunimoto and Hiroaki Ohfuji and Yohei Kojima and Toru Inoue and Tetsuo Irifune",

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doi = "10.1021/ic100474x",

language = "English",

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journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - CaCu3Pt4O12

T2 - The first perovskite with the B site fully occupied by Pt4+

AU - Yamada, Ikuya

AU - Takahashi, Yuka

AU - Ohgushi, Kenya

AU - Nishiyama, Norimasa

AU - Takahashi, Ryoji

AU - Wada, Kohei

AU - Kunimoto, Takehiro

AU - Ohfuji, Hiroaki

AU - Kojima, Yohei

AU - Inoue, Toru

AU - Irifune, Tetsuo

PY - 2010/8/2

Y1 - 2010/8/2

N2 - A novel A-site ordered perovskite CaCu3Pt4O 12 was synthesized under high pressure and high temperature of 12 GPa and 1250 °C. CaCu3Pt4O12 is the first perovskite in which the B site is fully occupied by Pt4+. The crystal structure refinement based on the synchrotron powder X-ray diffraction data shows that CaCu3Pt4O12 crystallizes in the space group Im3(cubic) with a lattice constant of a = 7.48946(10) Å. The magnetic susceptibility data show the antiferromagnetic transition at T N = 40 K, which is attributed to the magnetic ordering of Cu 2+ spins with S = 1/2.

AB - A novel A-site ordered perovskite CaCu3Pt4O 12 was synthesized under high pressure and high temperature of 12 GPa and 1250 °C. CaCu3Pt4O12 is the first perovskite in which the B site is fully occupied by Pt4+. The crystal structure refinement based on the synchrotron powder X-ray diffraction data shows that CaCu3Pt4O12 crystallizes in the space group Im3(cubic) with a lattice constant of a = 7.48946(10) Å. The magnetic susceptibility data show the antiferromagnetic transition at T N = 40 K, which is attributed to the magnetic ordering of Cu 2+ spins with S = 1/2.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

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ER -

CaCu₃Pt₄O₁₂: The first perovskite with the B site fully occupied by Pt⁴⁺

Abstract

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