Bulky cation effects on magnetoelectropolymerized polypyrrole

Iwao Mogi, K. Watanabe, M. Motokawa

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The redox behavior of p-toluenesulfonate-doped polypyrrole films was investigated in aqueous solutions containing various salts. It was found that the presence of bulky cations such as tetraethylammonium and pyridinium in the electrolytic solution hinders the redox processes of the films electropolymerized in magnetic fields above 0.2 T. This behavior was applied to a modified electrode with a wider potential window.

Original languageEnglish
Pages (from-to)198-201
Number of pages4
JournalJournal of Electroanalytical Chemistry
Volume507
Issue number1-2
DOIs
Publication statusPublished - 2001 Jul 13

Keywords

  • Bulky cation
  • Cation doping
  • Magnetic field effect
  • Polymer electrode

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemical Engineering(all)
  • Electrochemistry

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