Bulky cation effects on magnetoelectropolymerized polypyrrole

I. Mogi; K. Watanabe; M. Motokawa

doi:10.1016/S0022-0728(01)00359-X

Bulky cation effects on magnetoelectropolymerized polypyrrole

I. Mogi, K. Watanabe, M. Motokawa

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The redox behavior of p-toluenesulfonate-doped polypyrrole films was investigated in aqueous solutions containing various salts. It was found that the presence of bulky cations such as tetraethylammonium and pyridinium in the electrolytic solution hinders the redox processes of the films electropolymerized in magnetic fields above 0.2 T. This behavior was applied to a modified electrode with a wider potential window.

Original language	English
Pages (from-to)	198-201
Number of pages	4
Journal	Journal of Electroanalytical Chemistry
Volume	507
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-0728(01)00359-X
Publication status	Published - 2001 Jul 13

Keywords

Bulky cation
Cation doping
Magnetic field effect
Polymer electrode

ASJC Scopus subject areas

Analytical Chemistry
Chemical Engineering(all)
Electrochemistry

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10.1016/S0022-0728(01)00359-X

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abstract = "The redox behavior of p-toluenesulfonate-doped polypyrrole films was investigated in aqueous solutions containing various salts. It was found that the presence of bulky cations such as tetraethylammonium and pyridinium in the electrolytic solution hinders the redox processes of the films electropolymerized in magnetic fields above 0.2 T. This behavior was applied to a modified electrode with a wider potential window.",

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author = "I. Mogi and K. Watanabe and M. Motokawa",

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AU - Mogi, I.

AU - Watanabe, K.

AU - Motokawa, M.

PY - 2001/7/13

Y1 - 2001/7/13

N2 - The redox behavior of p-toluenesulfonate-doped polypyrrole films was investigated in aqueous solutions containing various salts. It was found that the presence of bulky cations such as tetraethylammonium and pyridinium in the electrolytic solution hinders the redox processes of the films electropolymerized in magnetic fields above 0.2 T. This behavior was applied to a modified electrode with a wider potential window.

AB - The redox behavior of p-toluenesulfonate-doped polypyrrole films was investigated in aqueous solutions containing various salts. It was found that the presence of bulky cations such as tetraethylammonium and pyridinium in the electrolytic solution hinders the redox processes of the films electropolymerized in magnetic fields above 0.2 T. This behavior was applied to a modified electrode with a wider potential window.

KW - Bulky cation

KW - Cation doping

KW - Magnetic field effect

KW - Polymer electrode

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U2 - 10.1016/S0022-0728(01)00359-X

DO - 10.1016/S0022-0728(01)00359-X

M3 - Article

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EP - 201

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

SN - 1572-6657

IS - 1-2

ER -

Bulky cation effects on magnetoelectropolymerized polypyrrole

Abstract

Keywords

ASJC Scopus subject areas

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