Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

Shohei Kumagai, Shinya Takaishi, Brian K. Breedlove, Hiroshi Okamoto, Hisaaki Tanaka, Shin Ichi Kurod, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)2Br](MalCn–Y)2·H2O (en = ethylenediamine; MalCn–Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12). The compound with n = 7 showed charge-bistability near room temperature. In addition, it is shown that the Pd(III) state is maintained in the thin film state.

Original languageEnglish
Pages (from-to)8382-8384
Number of pages3
JournalChemical Communications
Volume50
Issue number61
DOIs
Publication statusPublished - 2014 Jul 3

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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