Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

Shohei Kumagai; Shinya Takaishi; Brian K. Breedlove; Hiroshi Okamoto; Hisaaki Tanaka; Shin Ichi Kurod; Masahiro Yamashita

doi:10.1039/c4cc02547d

Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

Shohei Kumagai, Shinya Takaishi, Brian K. Breedlove, Hiroshi Okamoto, Hisaaki Tanaka, Shin Ichi Kurod, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)₂Br](MalC_n–Y)₂·H₂O (en = ethylenediamine; MalC_n–Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12). The compound with n = 7 showed charge-bistability near room temperature. In addition, it is shown that the Pd(III) state is maintained in the thin film state.

Original language	English
Pages (from-to)	8382-8384
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	61
DOIs	https://doi.org/10.1039/c4cc02547d
Publication status	Published - 2014 Jul 3

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature",

abstract = "We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)2Br](MalCn–Y)2·H2O (en = ethylenediamine; MalCn–Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12). The compound with n = 7 showed charge-bistability near room temperature. In addition, it is shown that the Pd(III) state is maintained in the thin film state.",

author = "Shohei Kumagai and Shinya Takaishi and Breedlove, {Brian K.} and Hiroshi Okamoto and Hisaaki Tanaka and Kurod, {Shin Ichi} and Masahiro Yamashita",

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doi = "10.1039/c4cc02547d",

language = "English",

volume = "50",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

AU - Kumagai, Shohei

AU - Takaishi, Shinya

AU - Breedlove, Brian K.

AU - Okamoto, Hiroshi

AU - Tanaka, Hisaaki

AU - Kurod, Shin Ichi

AU - Yamashita, Masahiro

PY - 2014/7/3

Y1 - 2014/7/3

N2 - We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)2Br](MalCn–Y)2·H2O (en = ethylenediamine; MalCn–Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12). The compound with n = 7 showed charge-bistability near room temperature. In addition, it is shown that the Pd(III) state is maintained in the thin film state.

AB - We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)2Br](MalCn–Y)2·H2O (en = ethylenediamine; MalCn–Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12). The compound with n = 7 showed charge-bistability near room temperature. In addition, it is shown that the Pd(III) state is maintained in the thin film state.

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DO - 10.1039/c4cc02547d

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SP - 8382

EP - 8384

JO - Chemical Communications

JF - Chemical Communications

IS - 61

ER -

Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

Abstract

ASJC Scopus subject areas

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