Bottom-up synthesis and thread-in-bead structures of finite (n,0)-zigzag single-wall carbon nanotubes

Shunpei Hitosugi, Takashi Yamasaki, Hiroyuki Isobe

Research output: Contribution to journalArticlepeer-review

128 Citations (Scopus)

Abstract

The last remaining synthetic target of finite single-wall carbon nanotube models, the zigzag nanotube, has been accomplished through bottom-up chemical synthesis. The zigzag nanotube was synthetically accessible without constructing long-sought yet elusive cyclacene structures but with a cycloarylene structure by devising its cutout positions. The persistent tubular shape was also perfected in this last model by cyclization of zigzag-shaped aromatic molecules with a synchronous topological arrangement. The crystal structure of this nanotube further revealed an entangled supramolecular assembly, which showed a novel way to align nanotube molecules by utilizing their open-end functional groups in a thread-in-bead molecular assembly.

Original languageEnglish
Pages (from-to)12442-12445
Number of pages4
JournalJournal of the American Chemical Society
Volume134
Issue number30
DOIs
Publication statusPublished - 2012 Aug 1

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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