Bis(Ethylenethio)tetraselenafulvalene and related hybrid diselenadithiafulvalenes as novel electron donors forming highly conductive complexes with 7,7,8,8-tetracyanoquinodimethane

Mie Kodani; Satoshi Murakami; Tetsuya Jigami; Kazuo Takimiya; Yoshio Aso; Tetsuo Otsubo

Bis(Ethylenethio)tetraselenafulvalene and related hybrid diselenadithiafulvalenes as novel electron donors forming highly conductive complexes with 7,7,8,8-tetracyanoquinodimethane

Mie Kodani, Satoshi Murakami, Tetsuya Jigami, Kazuo Takimiya, Yoshio Aso, Tetsuo Otsubo

Research output: Contribution to journal › Article › peer-review

Abstract

The title tetraselenafulvalene (BET-TSF) and four related hybrid diselenadithiafulvalenes (STF) have been synthesized as a five-membered heterocycle-fused tetrathiafulvalene type of novel electron donors, which form highly conducting molecular complexes with 7,7,8,8-tetracyanoquinodimethane. In particular, the complex of BET-TSF shows a room-temperature conductivity of 2600 S cm^-1 which is of the highest class for a molecular complex.

Original language	English
Pages (from-to)	225-235
Number of pages	11
Journal	Heterocycles
Volume	54
Issue number	1
Publication status	Published - 2001 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

Cite this

Bis(Ethylenethio)tetraselenafulvalene and related hybrid diselenadithiafulvalenes as novel electron donors forming highly conductive complexes with 7,7,8,8-tetracyanoquinodimethane. / Kodani, Mie; Murakami, Satoshi; Jigami, Tetsuya; Takimiya, Kazuo; Aso, Yoshio; Otsubo, Tetsuo.

In: Heterocycles, Vol. 54, No. 1, 01.01.2001, p. 225-235.

Research output: Contribution to journal › Article › peer-review

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Bis(Ethylenethio)tetraselenafulvalene and related hybrid diselenadithiafulvalenes as novel electron donors forming highly conductive complexes with 7,7,8,8-tetracyanoquinodimethane

Abstract

ASJC Scopus subject areas

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