TY - JOUR
T1 - Biologically Active Glycosides from Asteroidea, XXIX. X‐Ray Crystallographic Analysis of Desulfated Asterosaponin P1 Isolated from the Starfish Asterina pectinifera
AU - Cho, Yuko
AU - Higuchi, Ryuichi
AU - Marubayashi, Nobuhiro
AU - Ueda, Ikuhiko
AU - Komori, Tetsuya
PY - 1992/1/1
Y1 - 1992/1/1
N2 - By X‐ray crystallographic analysis of desulfated asterosaponin P1 the absolute configuration at C‐24 in the aglycone moiety is confirmed. The unique conformation of the side chain part possessing the carbohydrate moiety is also revealed. This is the first report of an X‐ray crystallographic analysis of a steroid glycoside whose carbohydrate moiety is located in the C‐17 side chain.
AB - By X‐ray crystallographic analysis of desulfated asterosaponin P1 the absolute configuration at C‐24 in the aglycone moiety is confirmed. The unique conformation of the side chain part possessing the carbohydrate moiety is also revealed. This is the first report of an X‐ray crystallographic analysis of a steroid glycoside whose carbohydrate moiety is located in the C‐17 side chain.
KW - Asterina pectinifera
KW - Asterosaponin P, desulfated
KW - Starfish
KW - Steroid glycoside
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U2 - 10.1002/jlac.199219920116
DO - 10.1002/jlac.199219920116
M3 - Article
AN - SCOPUS:84986674077
SN - 1434-193X
VL - 1992
SP - 79
EP - 81
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
IS - 1
ER -