Bimetallic Co-Pd alloy nanoparticles as magnetically recoverable catalysts for the aerobic oxidation of alcohols in water

Yoshikazu Ito; Hidetoshi Ohta; Yoichi M.A. Yamada; Toshiaki Enoki; Yasuhiro Uozumi

doi:10.1016/j.tet.2014.03.108

Bimetallic Co-Pd alloy nanoparticles as magnetically recoverable catalysts for the aerobic oxidation of alcohols in water

Yoshikazu Ito, Hidetoshi Ohta, Yoichi M.A. Yamada, Toshiaki Enoki, Yasuhiro Uozumi

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Co-Pd bimetallic alloy nanoparticle catalysts were prepared from CoCl₂, Pd(OAc)₂ and several capping agents with Li(C₂H₅)₃BH. The nanoparticle catalysts were applied to the aerobic oxidation of a variety of alcohols in water to give the corresponding carbonyl products. The catalyst was magnetically recovered and reused for further oxidation. The nanoparticle catalysts were characterized with TEM, ICP, and XPS analyses.

Original language	English
Pages (from-to)	6146-6149
Number of pages	4
Journal	Tetrahedron
Volume	70
Issue number	36
DOIs	https://doi.org/10.1016/j.tet.2014.03.108
Publication status	Published - 2014 Sept 9

Keywords

Aerobic oxidation
Bimetallic catalyst
Cobalt-palladium
Magnetic nanoparticle
Water

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2014.03.108

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title = "Bimetallic Co-Pd alloy nanoparticles as magnetically recoverable catalysts for the aerobic oxidation of alcohols in water",

abstract = "Co-Pd bimetallic alloy nanoparticle catalysts were prepared from CoCl2, Pd(OAc)2 and several capping agents with Li(C2H5)3BH. The nanoparticle catalysts were applied to the aerobic oxidation of a variety of alcohols in water to give the corresponding carbonyl products. The catalyst was magnetically recovered and reused for further oxidation. The nanoparticle catalysts were characterized with TEM, ICP, and XPS analyses.",

keywords = "Aerobic oxidation, Bimetallic catalyst, Cobalt-palladium, Magnetic nanoparticle, Water",

author = "Yoshikazu Ito and Hidetoshi Ohta and Yamada, {Yoichi M.A.} and Toshiaki Enoki and Yasuhiro Uozumi",

note = "Funding Information: We thank RIKEN for XPS (Dr. Aiko Nakao), TEM (Ms. Tomoka Kikitsu) and ICP-AES (Ms. Chieko Kariya) analyses. We gratefully acknowledge financial support from JST ACT-C , JST CREST , JSPS (# 24550126 , # 20655035 and # 2105 ), Takeda Science Foundation , the Naito Foundation , and RIKEN . Y.I. was supported by JPSP Fellowship . Publisher Copyright: {\textcopyright} 2014 Elsevier Ltd.",

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doi = "10.1016/j.tet.2014.03.108",

language = "English",

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T1 - Bimetallic Co-Pd alloy nanoparticles as magnetically recoverable catalysts for the aerobic oxidation of alcohols in water

AU - Ito, Yoshikazu

AU - Ohta, Hidetoshi

AU - Yamada, Yoichi M.A.

AU - Enoki, Toshiaki

AU - Uozumi, Yasuhiro

N1 - Funding Information: We thank RIKEN for XPS (Dr. Aiko Nakao), TEM (Ms. Tomoka Kikitsu) and ICP-AES (Ms. Chieko Kariya) analyses. We gratefully acknowledge financial support from JST ACT-C , JST CREST , JSPS (# 24550126 , # 20655035 and # 2105 ), Takeda Science Foundation , the Naito Foundation , and RIKEN . Y.I. was supported by JPSP Fellowship . Publisher Copyright: © 2014 Elsevier Ltd.

PY - 2014/9/9

Y1 - 2014/9/9

N2 - Co-Pd bimetallic alloy nanoparticle catalysts were prepared from CoCl2, Pd(OAc)2 and several capping agents with Li(C2H5)3BH. The nanoparticle catalysts were applied to the aerobic oxidation of a variety of alcohols in water to give the corresponding carbonyl products. The catalyst was magnetically recovered and reused for further oxidation. The nanoparticle catalysts were characterized with TEM, ICP, and XPS analyses.

AB - Co-Pd bimetallic alloy nanoparticle catalysts were prepared from CoCl2, Pd(OAc)2 and several capping agents with Li(C2H5)3BH. The nanoparticle catalysts were applied to the aerobic oxidation of a variety of alcohols in water to give the corresponding carbonyl products. The catalyst was magnetically recovered and reused for further oxidation. The nanoparticle catalysts were characterized with TEM, ICP, and XPS analyses.

KW - Aerobic oxidation

KW - Bimetallic catalyst

KW - Cobalt-palladium

KW - Magnetic nanoparticle

KW - Water

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DO - 10.1016/j.tet.2014.03.108

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SN - 0040-4020

VL - 70

SP - 6146

EP - 6149

JO - Tetrahedron

JF - Tetrahedron

IS - 36

ER -

Bimetallic Co-Pd alloy nanoparticles as magnetically recoverable catalysts for the aerobic oxidation of alcohols in water

Abstract

Keywords

ASJC Scopus subject areas

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