Bicontinuous periodic patterns of block copolymers - Structural analysis based on curvature distributions

Hiroshi Jinnai, Yukihiro Nishikawa, Hirokazu Hasegawa

Research output: Contribution to journalArticlepeer-review

Abstract

Bicontinuous microdomain structures appearing in diblock copolymers with copolymer composition of ca. 34∼ 38% are studied from the viewpoint of interface curvatures. Since interface minimization is a major driving force of the structure formation in such systems, infinite periodic minimal surfaces (IPMS) with a variety of symmetries (or space groups) are often used as models. However, characterization of a bicontinuous structure often involves a controversial decision about which type of IPMS to employ. This decision is difficult because only two-dimensional images of the structures can be usually obtained by conventional transmission electron microscopy (TEM) and many IPMS reproduce a similar image in projection. However, recent developement of three-dimensional imaging of nm scale structures by TEM enabled us to measure the local interface curvatures. In the present study, we demonstrate that the local curvature distribution is a sensitive measure to distinguish the type of IPMS and hence the space group of the bicontinuous structures.

Original languageEnglish
Pages (from-to)837-844
Number of pages8
JournalKOBUNSHI RONBUNSHU
Volume56
Issue number12
DOIs
Publication statusPublished - 1999
Externally publishedYes

Keywords

  • Block Copolymers
  • Curvature Distributions
  • Infinite Periodic Minimal Surfaces
  • Interface Curvature
  • Microphase Separation

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Materials Science (miscellaneous)
  • Environmental Science(all)
  • Polymers and Plastics

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