Ba19in9N9, a subnitride containing isolated [In5]5- and [In8]12- Zintl anions

Hisanori Yamane, Shinya Sasaki, Takashi Kajiwara, Takahiro Yamada, Masahiko Shimada

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Single crystals of nonadecabarium nonaindium nonanitride, Ba 19In9N9, were synthesized by the Na flux method under N2 pressure. The compound crystallizes in the monoclinic space group C2/m, with Z = 2. Polyanionic indium clusters [In5] 5- and [In8]12- are surrounded by Ba 2+ cations and are located in a flat cage built of linked nitrogen-centred NBa6 octahedra. The structural formula is expressed as (Ba38N18)[In5]2[In8].

Original languageEnglish
Pages (from-to)i120-i123
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number10
DOIs
Publication statusPublished - 2004 Oct 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Ba<sub>19</sub>in<sub>9</sub>N<sub>9</sub>, a subnitride containing isolated [In<sub>5</sub>]<sup>5-</sup> and [In<sub>8</sub>]<sup>12-</sup> Zintl anions'. Together they form a unique fingerprint.

Cite this