Auger-free luminescence characteristics of Rb1 1 xCsxCaCl3

Keisuke Takahashi, Masanori Koshimizu, Yutaka Fujimoto, Takayuki Yanagida, Keisuke Asai

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Fast scintillation materials based on ternary halide mixed crystals, Rb1 1 xCsxCaCl3 were synthesized. Broad luminescence bands were observed around 360 nm and can be ascribed to Auger-free Luminescence (AFL) for vacuum ultraviolet core-level excitation. Several luminescence bands for interband excitation were also observed. For X-ray excitation, the band that is ascribed to AFL could be clearly detected. The scintillation decay components due to the AFL had decay time constant of 0.8 ns for RbCaCl3 and 2.0 ns for Rb1 1 xCsxCaCl3 (x º0). CsCaCl3 had the largest light yield of the AFL component, exceeding 1200 photons/MeV, which was slightly lower than that of BaF2. The light yield of the AFL component increased linearly with Cs content.

Original languageEnglish
Pages (from-to)755-760
Number of pages6
JournalJournal of the Ceramic Society of Japan
Volume126
Issue number10
DOIs
Publication statusPublished - 2018 Oct

Keywords

  • Auger-free luminescence
  • Core hole
  • Core-valence luminescence
  • Scintillator

ASJC Scopus subject areas

  • Ceramics and Composites
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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