Abstract
A study on Auger-electron spectra of F3SiCH2CH2Si(CH3)3 was performed by using monochromatized synchrotron radiation. The normal Si:L23VV Auger-electron spectrum was measured in the vapor phase and characterized through the ab initio molecular orbital calculation. The cascade Si:L23VV Auger-electron spectra were also obtained by L23-holes creation through Si:KL23L23 Auger transitions after Si:1s photoexcitation in the vapor phase or its photoelectron emission in the condensed phase. Further the C:KVV and F:KVV Auger-electron spectra were measured and discussed in comparison with those of some related molecules.
Original language | English |
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Pages (from-to) | 14-20 |
Number of pages | 7 |
Journal | Journal of Electron Spectroscopy and Related Phenomena |
Volume | 175 |
Issue number | 1-3 |
DOIs | |
Publication status | Published - 2009 Jan 1 |
Keywords
- Auger-electron
- C:KVV
- Cascade Auger-electron
- F:KVV
- Organosilicon molecule
- Si:LVV
- Site-specific fragmentation
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Radiation
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics
- Spectroscopy
- Physical and Theoretical Chemistry