TY - JOUR
T1 - Auger electron spectra of CF 3 CN, CF 3 Cl, CF 2 Cl 2 and CFCl 3
AU - Shimizu, Y.
AU - Ueda, K.
AU - Chiba, H.
AU - Okunishi, M.
AU - Ohmori, K.
AU - Sato, Y.
AU - Suzuki, I. H.
AU - Ibuki, T.
AU - Okada, K.
N1 - Funding Information:
We thank Prof. A. P. Hitchcock for his comments on the ionization energies of two carbons in CF 3 CN. This work was partially supported by the grants-in-aid for Scientific Research from the Ministry of Education, Science, and Culture, Japan.
PY - 1999/6/15
Y1 - 1999/6/15
N2 - The F KVV and Cl LVV Auger electron spectra of the chlorofluorocarbon molecules CF3Cl, CF2Cl2 and CFCl3, as well as the F, N and C KVV Auger spectra of the CF3CN molecule, have been observed using electron-impact excitation. The spectra have been interpreted with the help of ab initio calculations for the local density of states. The fragmentations specific to the atomic site where the core hole is created, observed for these molecules, are discussed in connection of characters of the Auger final states analyzed in the present study.
AB - The F KVV and Cl LVV Auger electron spectra of the chlorofluorocarbon molecules CF3Cl, CF2Cl2 and CFCl3, as well as the F, N and C KVV Auger spectra of the CF3CN molecule, have been observed using electron-impact excitation. The spectra have been interpreted with the help of ab initio calculations for the local density of states. The fragmentations specific to the atomic site where the core hole is created, observed for these molecules, are discussed in connection of characters of the Auger final states analyzed in the present study.
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U2 - 10.1016/S0301-0104(99)00062-2
DO - 10.1016/S0301-0104(99)00062-2
M3 - Article
AN - SCOPUS:0033419479
VL - 244
SP - 439
EP - 448
JO - Chemical Physics
JF - Chemical Physics
SN - 0301-0104
IS - 2-3
ER -