Auger electron spectra of CF 3 CN, CF 3 Cl, CF 2 Cl 2 and CFCl 3

Y. Shimizu; K. Ueda; H. Chiba; M. Okunishi; K. Ohmori; Y. Sato; I. H. Suzuki; T. Ibuki; K. Okada

doi:10.1016/S0301-0104(99)00062-2

Auger electron spectra of CF ₃ CN, CF ₃ Cl, CF ₂ Cl ₂ and CFCl ₃

Y. Shimizu, K. Ueda, H. Chiba, M. Okunishi, K. Ohmori, Y. Sato, I. H. Suzuki, T. Ibuki, K. Okada

Division of Measurements

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The F KVV and Cl LVV Auger electron spectra of the chlorofluorocarbon molecules CF₃Cl, CF₂Cl₂ and CFCl₃, as well as the F, N and C KVV Auger spectra of the CF₃CN molecule, have been observed using electron-impact excitation. The spectra have been interpreted with the help of ab initio calculations for the local density of states. The fragmentations specific to the atomic site where the core hole is created, observed for these molecules, are discussed in connection of characters of the Auger final states analyzed in the present study.

Original language	English
Pages (from-to)	439-448
Number of pages	10
Journal	Chemical Physics
Volume	244
Issue number	2-3
DOIs	https://doi.org/10.1016/S0301-0104(99)00062-2
Publication status	Published - 1999 Jun 15

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Auger electron spectra of CF 3 CN, CF 3 Cl, CF 2 Cl 2 and CFCl 3",

abstract = "The F KVV and Cl LVV Auger electron spectra of the chlorofluorocarbon molecules CF3Cl, CF2Cl2 and CFCl3, as well as the F, N and C KVV Auger spectra of the CF3CN molecule, have been observed using electron-impact excitation. The spectra have been interpreted with the help of ab initio calculations for the local density of states. The fragmentations specific to the atomic site where the core hole is created, observed for these molecules, are discussed in connection of characters of the Auger final states analyzed in the present study.",

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T1 - Auger electron spectra of CF 3 CN, CF 3 Cl, CF 2 Cl 2 and CFCl 3

AU - Shimizu, Y.

AU - Ueda, K.

AU - Chiba, H.

AU - Okunishi, M.

AU - Ohmori, K.

AU - Sato, Y.

AU - Suzuki, I. H.

AU - Ibuki, T.

AU - Okada, K.

PY - 1999/6/15

Y1 - 1999/6/15

N2 - The F KVV and Cl LVV Auger electron spectra of the chlorofluorocarbon molecules CF3Cl, CF2Cl2 and CFCl3, as well as the F, N and C KVV Auger spectra of the CF3CN molecule, have been observed using electron-impact excitation. The spectra have been interpreted with the help of ab initio calculations for the local density of states. The fragmentations specific to the atomic site where the core hole is created, observed for these molecules, are discussed in connection of characters of the Auger final states analyzed in the present study.

AB - The F KVV and Cl LVV Auger electron spectra of the chlorofluorocarbon molecules CF3Cl, CF2Cl2 and CFCl3, as well as the F, N and C KVV Auger spectra of the CF3CN molecule, have been observed using electron-impact excitation. The spectra have been interpreted with the help of ab initio calculations for the local density of states. The fragmentations specific to the atomic site where the core hole is created, observed for these molecules, are discussed in connection of characters of the Auger final states analyzed in the present study.

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