Atomic-order thermal nitridation of Si(100) and subsequent growth of Si

T. Watanabe, M. Sakuraba, T. Matsuura, J. Murota

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11 Citations (Scopus)

Abstract

Atomic-order nitridation by [formula omitted] on Si(100) and subsequent Si growth by [formula omitted] were investigated using an ultraclean low-pressure chemical vapor deposition system with a Xe flash lamp. In thermal nitridation on Si(100), it is found that nitridation occurs even at 260 °C with flash heating, and the N atom concentration tends to saturate to about [formula omitted] In Si deposition on the ultrathin Si nitride, it is found that N desorption from the Si nitride films hardly occurs, and Si grew on Si nitride at 385 °C in an [formula omitted] environment with and without the flash lamp light irradiation. An incubation period of Si growth is observed and increases with increasing N atom concentration of the Si nitride film. On Si with N atom concentration of about [formula omitted] the incubation period is hardly observed and the reflection high energy electron diffraction patterns indicates that Si epitaxially grew. Layer-by-layer growth control of Si nitride is proposed by combining atomic-order nitridation on Si and atomic-layer growth of Si on the Si nitride.

Original languageEnglish
Pages (from-to)1907-1911
Number of pages5
JournalJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
Volume19
Issue number4
DOIs
Publication statusPublished - 2001 Jul

Keywords

  • Si

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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