Abstract
Atomic-order nitridation of ∼30 Å thick SiO2 has been investigated by an electron-cyclotron-resonance nitrogen plasma. It is found that the number of nitrogen atoms in the nitrided SiO2 film increases with plasma exposure time and tends to saturate. In the initial nitridation of SiO2, the number of nitrogen atoms in the nitrided SiO2 film depends mainly on the number of incident ions, in dependence on the surface temperature. In the saturation region of the nitridation, it is found that the nitrogen concentration and the depth of the nitrided SiO2 increase with increasing ion energy as well as surface temperature. In the nitridation of SiO2, it is found that the nitrogen bonding structure in the nitrided SiO2 film is changed by ion irradiation with an energy of ∼12 eV and by the temperature increase of the irradiated surface.
Original language | English |
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Pages (from-to) | 451-455 |
Number of pages | 5 |
Journal | Surface and Interface Analysis |
Volume | 34 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2002 Aug 1 |
Event | ECASIA'01 Proceedings of the 9th European Conference on Applications of Suface and Interface Analysis - Avignon, France Duration: 2001 Sep 30 → 2001 Oct 5 |
Keywords
- Atomic-order nitridation
- Ion energy
- Nitrogen plasma
- Radical and ion
- SiO
- XPS
ASJC Scopus subject areas
- Chemistry(all)
- Condensed Matter Physics
- Surfaces and Interfaces
- Surfaces, Coatings and Films
- Materials Chemistry