Asymmetric total synthesis of pinnaic acid

Shu Xu; Hirokazu Arimoto; Daisuke Uemura

doi:10.1002/anie.200701581

Asymmetric total synthesis of pinnaic acid

Shu Xu, Hirokazu Arimoto, Daisuke Uemura

LIF - Molecular and Chemical Life Science

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Pinned together: Asymmetric total synthesis of pinnaic acid was accomplished through a stereospecific route that features as key steps a Pd-catalyzed trimethylenemethane (TMM) [3+2] cyclization, a four-step tandem hydrogenation-cyclization, and cross-olefin-metathesis reactions (see scheme). (Chemical Equation Presented).

Original language	English
Pages (from-to)	5746-5749
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	30
DOIs	https://doi.org/10.1002/anie.200701581
Publication status	Published - 2007 Aug 3

Keywords

Alkaloids
Asymmetric synthesis
Metathesis
Natural products
Total synthesis

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200701581

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AU - Arimoto, Hirokazu

AU - Uemura, Daisuke

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KW - Asymmetric synthesis

KW - Metathesis

KW - Natural products

KW - Total synthesis

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Asymmetric total synthesis of pinnaic acid

Abstract

Keywords

ASJC Scopus subject areas

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