Abstract
Pinned together: Asymmetric total synthesis of pinnaic acid was accomplished through a stereospecific route that features as key steps a Pd-catalyzed trimethylenemethane (TMM) [3+2] cyclization, a four-step tandem hydrogenation-cyclization, and cross-olefin-metathesis reactions (see scheme). (Chemical Equation Presented).
| Original language | English |
|---|---|
| Pages (from-to) | 5746-5749 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 46 |
| Issue number | 30 |
| DOIs | |
| Publication status | Published - 2007 Aug 3 |
Keywords
- Alkaloids
- Asymmetric synthesis
- Metathesis
- Natural products
- Total synthesis
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Xu, S., Arimoto, H., & Uemura, D. (2007). Asymmetric total synthesis of pinnaic acid. Angewandte Chemie - International Edition, 46(30), 5746-5749. https://doi.org/10.1002/anie.200701581