Asymmetric synthesis of N-(diphenylphosphinyl)amines promoted by chiral carbosilane dendritic ligands in the enantioselective addition of dialkylzinc compounds to N-(diphenylphosphinyl)imines

Itaru Sato, Kenji Hosoi, Ryo Kodaka, Kenso Soai

Research output: Contribution to journalArticlepeer-review

29 Citations (Scopus)

Abstract

The enantioselective addition of dialkylzinc compounds to N- (diphenylphosphinyl)imines by using chiral dendrimers with flexible carbosilane backbones gives enantiomerically enriched N-(diphenylphosphinyl)amines with up to 92% ee.

Original languageEnglish
Pages (from-to)3115-3118
Number of pages4
JournalEuropean Journal of Organic Chemistry
Issue number18
DOIs
Publication statusPublished - 2002 Sep

Keywords

  • Alkylation
  • Amines
  • Asymmetric synthesis
  • Dendrimers
  • Imines

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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