Asymmetric synthesis of N-diphenylphosphinoylamines by solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines

Itaru Sato, Ryo Kodaka, Kenso Soai

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Solvent-free enantioselective addition of dialkylzincs to N-diphenylphosphinoylimines in the presence of chiral 2-morpholino-1-phenylpropan-1-ol affords N-diphenylphosphinoylamines with up to 97% ee. The reaction in the solvent-free system is faster than in organic solvents.

Original languageEnglish
Pages (from-to)2912-2914
Number of pages3
JournalJournal of the Chemical Society. Perkin Transactions 1
Volume1
Issue number22
DOIs
Publication statusPublished - 2001 Oct 15

ASJC Scopus subject areas

  • Chemistry(all)

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