TY - JOUR
T1 - Asymmetric Activation of Racemic Catalysts
AU - Mikami, Koichi
AU - Korenaga, Toshinobu
AU - Matsukawa, Satoru
AU - Matsumoto, Yousuke
AU - Ding, Kuiling
AU - Ishii, Akihiro
AU - Volk, Thorsten
AU - Terada, Masahiro
PY - 1998/1/1
Y1 - 1998/1/1
N2 - In asymmetric catalytic reactions, racemic catalysts inherently give only racemic products, whereas non-racemic catalysts generate non-racemic products with or without a non-linear relationship. Conversely, we report herein as an account a conceptually new strategy for asymmetric catalysis using racemic catalysts wherein a chiral additive selectively activates, rather than de-activates, one enantiomer of the racemic catalyst.
AB - In asymmetric catalytic reactions, racemic catalysts inherently give only racemic products, whereas non-racemic catalysts generate non-racemic products with or without a non-linear relationship. Conversely, we report herein as an account a conceptually new strategy for asymmetric catalysis using racemic catalysts wherein a chiral additive selectively activates, rather than de-activates, one enantiomer of the racemic catalyst.
UR - http://www.scopus.com/inward/record.url?scp=1542465850&partnerID=8YFLogxK
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U2 - 10.5059/yukigoseikyokaishi.56.975
DO - 10.5059/yukigoseikyokaishi.56.975
M3 - Article
AN - SCOPUS:1542465850
VL - 56
SP - 975
EP - 986
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
SN - 0037-9980
IS - 11
ER -