Asymmetric 1,4-addition of aryltrialkoxysilanes to α,β-unsaturated esters and amides catalyzed by a chiral rhodium complex

Shuichi Oi, Akio Taira, Yoshio Honma, Takashi Sato, Yoshio Inoue

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

A highly enantioselective 1,4-addition of aryltrialkoxysilanes to α,β-unsaturated esters and amides was successfully catalyzed by a chiral rhodium complex generated from [Rh(cod)(MeCN)2]BF4 and (S)-BINAP.

Original languageEnglish
Pages (from-to)598-602
Number of pages5
JournalTetrahedron Asymmetry
Volume17
Issue number4
DOIs
Publication statusPublished - 2006 Feb 20

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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