TY - JOUR
T1 - As-Heteropentacenes
T2 - An Experimental and Computational Study on a Novel Class of Heteroacenes
AU - Imoto, Hiroaki
AU - Fujii, Toshiki
AU - Tanaka, Susumu
AU - Yamamoto, Shunsuke
AU - Mitsuishi, Masaya
AU - Yumura, Takashi
AU - Naka, Kensuke
N1 - Funding Information:
We thank Prof. M. Shimizu, Mr. K. Nishimura, and Mr. M. Sakai of the Kyoto Institute of Technology for emission lifetime measurements. The film XRD measurements were supported by the Material Solutions Center (MaSC), Tohoku University, Japan. This study was supported by JSPS KAKENHI Grant Number JP17H05369 (Coordination Asymmetry).
PY - 2018/9/21
Y1 - 2018/9/21
N2 - Arsenic-containing heteropentacenes were synthesized for the first time; bibenzofuran, benzothienyl benzofuran, and bibenzothiophene were bridged by arsenic atoms. Their structures and properties were experimentally and computationally studied using X-ray crystallography, optical and electronic properties, aromaticity, charge carrier mobility, etc. The present findings on the novel class of heteroacenes will expand functional organic chemistry.
AB - Arsenic-containing heteropentacenes were synthesized for the first time; bibenzofuran, benzothienyl benzofuran, and bibenzothiophene were bridged by arsenic atoms. Their structures and properties were experimentally and computationally studied using X-ray crystallography, optical and electronic properties, aromaticity, charge carrier mobility, etc. The present findings on the novel class of heteroacenes will expand functional organic chemistry.
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U2 - 10.1021/acs.orglett.8b02660
DO - 10.1021/acs.orglett.8b02660
M3 - Article
C2 - 30207479
AN - SCOPUS:85053538090
VL - 20
SP - 5952
EP - 5955
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 18
ER -