Application of laser induced photoacoustic spectroscopy to the determination of 99Tc

Tsutomu Sekine, Masayuki Hiraga, Tsutomu Fujita, Abdul Mutalib, Kenji Yoshihara

Research output: Contribution to journalArticle

Abstract

Laser induced photoacoustic spectroscopy was applied to the determination of 99Tc in a solution coupled with quantitative complexation of Tc with to (thiourea) to form Tc(tu)63+. The complexation procedure was adopted to shift the uv absorption peak of pertechnetate to the visible region. Photoacoustic signals due to the 488 nm absorption peak of Tc(tu)63+ was analyzed by using a Fast Fourrier Transform (FFT) system. The quantitative detection of Tc could be easily performed down to the 10-8 M concentration in this system. This is about 1,000 times more sensitive than the ordinary colorimetric measurement.

Original languageEnglish
Pages (from-to)1131-1135
Number of pages5
Journaljournal of nuclear science and technology
Volume30
Issue number11
DOIs
Publication statusPublished - 1993 Jan 1

Keywords

  • PZT detection
  • determination
  • environmental pollution
  • hexakis thiourea technetium (III)
  • laser induced photoacoustic spectroscopy
  • photoacoustic effect
  • technetium 99
  • wavelength shifter

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Nuclear Energy and Engineering

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