Application of laser induced photoacoustic spectroscopy to the determination of99Tc

Tsutomu Sekine, Masayuki Hiraga, Tsutomu Fujita, Abdul Mutalib, Kenji Yoshihara

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

Laser induced photoacoustic spectroscopy was applied to the determination of99Tc in a solution coupled with quantitative complexation of Tc with tu (thiourea) to form Tc(tu)63+ The complexation procedure was adopted to shift the uv absorption peak of pertechnetate to the visible region. Photoacoustic signals due to the 488nm absorption peak of Tc(tu)63+was analyzed by using a Fast Fourrier Transform (FFT) system. The quantitative detection of Tc could be easily performed down to the 10-8M concentration in this system. This is about 1,000 times more sensitive than the ordinary colorimetric measurement.

Original languageEnglish
Pages (from-to)1131-1135
Number of pages5
Journaljournal of nuclear science and technology
Volume30
Issue number11
DOIs
Publication statusPublished - 1993 Nov

Keywords

  • Determination
  • Environmental pollution
  • Hexakis thiourea technetium (III)
  • Laser induced photoacoustic spectroscopy
  • PZT detection
  • Photoacoustic effect
  • Technetium 99
  • Wavelength shifter

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Nuclear Energy and Engineering

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