Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe

Tomoko Haraga; Shingo Saito; Yoshiyuki Sato; Shiho Asai; Yukiko Hanzawa; Hitoshi Hoshino; Masami Shibukawa; Ken Ichiro Ishimori; Kuniaki Takahashi

doi:10.2116/analsci.30.773

Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe

Tomoko Haraga, Shingo Saito, Yoshiyuki Sato, Shiho Asai, Yukiko Hanzawa, Hitoshi Hoshino, Masami Shibukawa, Ken Ichiro Ishimori, Kuniaki Takahashi

Environmental Studies

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Abstract

A simple and rapid method with low radiation exposure risk was developed for the determination of neodymium in spent nuclear fuel by capillary electrophoresis with laser-induced fluorescence detection using a fluorescent probe having a macrocyclic hexadentate polyaminocarboxylate structure. The concentration of Nd(III) in a spent nuclear fuel sample was determined with no interference from various matrix elements, including lanthanides and uranium (at a 200-fold excess), with 92 ± 3% recovery. This is due to high resolution based on establishing a ternary complex equilibrium during migration in which the hydroxyl ion plays an auxiliary role (log K_Ln-L-OH = 3.9-5.3).

Original language	English
Pages (from-to)	773-776
Number of pages	4
Journal	analytical sciences
Volume	30
Issue number	7
DOIs	https://doi.org/10.2116/analsci.30.773
Publication status	Published - 2014

Keywords

Burnup
Capillary electrophoresis
Fluorescence detection
High-level radioactive wastes
Neodymium
Polyaminocarboxylate
Spent nuclear fuel
Ternary complex formation

ASJC Scopus subject areas

Analytical Chemistry

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Haraga, T., Saito, S., Sato, Y., Asai, S., Hanzawa, Y., Hoshino, H., Shibukawa, M., Ishimori, K. I., & Takahashi, K. (2014). Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe. analytical sciences, 30(7), 773-776. https://doi.org/10.2116/analsci.30.773

Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe. / Haraga, Tomoko; Saito, Shingo; Sato, Yoshiyuki; Asai, Shiho; Hanzawa, Yukiko; Hoshino, Hitoshi; Shibukawa, Masami; Ishimori, Ken Ichiro; Takahashi, Kuniaki.

In: analytical sciences, Vol. 30, No. 7, 2014, p. 773-776.

Research output: Contribution to journal › Article › peer-review

Haraga, T, Saito, S, Sato, Y, Asai, S, Hanzawa, Y, Hoshino, H, Shibukawa, M, Ishimori, KI & Takahashi, K 2014, 'Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe', analytical sciences, vol. 30, no. 7, pp. 773-776. https://doi.org/10.2116/analsci.30.773

Haraga, Tomoko ; Saito, Shingo ; Sato, Yoshiyuki ; Asai, Shiho ; Hanzawa, Yukiko ; Hoshino, Hitoshi ; Shibukawa, Masami ; Ishimori, Ken Ichiro ; Takahashi, Kuniaki. / Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe. In: analytical sciences. 2014 ; Vol. 30, No. 7. pp. 773-776.

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title = "Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe",

abstract = "A simple and rapid method with low radiation exposure risk was developed for the determination of neodymium in spent nuclear fuel by capillary electrophoresis with laser-induced fluorescence detection using a fluorescent probe having a macrocyclic hexadentate polyaminocarboxylate structure. The concentration of Nd(III) in a spent nuclear fuel sample was determined with no interference from various matrix elements, including lanthanides and uranium (at a 200-fold excess), with 92 ± 3% recovery. This is due to high resolution based on establishing a ternary complex equilibrium during migration in which the hydroxyl ion plays an auxiliary role (log KLn-L-OH = 3.9-5.3).",

keywords = "Burnup, Capillary electrophoresis, Fluorescence detection, High-level radioactive wastes, Neodymium, Polyaminocarboxylate, Spent nuclear fuel, Ternary complex formation",

author = "Tomoko Haraga and Shingo Saito and Yoshiyuki Sato and Shiho Asai and Yukiko Hanzawa and Hitoshi Hoshino and Masami Shibukawa and Ishimori, {Ken Ichiro} and Kuniaki Takahashi",

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AU - Haraga, Tomoko

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AU - Sato, Yoshiyuki

AU - Asai, Shiho

AU - Hanzawa, Yukiko

AU - Hoshino, Hitoshi

AU - Shibukawa, Masami

AU - Ishimori, Ken Ichiro

AU - Takahashi, Kuniaki

PY - 2014

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AB - A simple and rapid method with low radiation exposure risk was developed for the determination of neodymium in spent nuclear fuel by capillary electrophoresis with laser-induced fluorescence detection using a fluorescent probe having a macrocyclic hexadentate polyaminocarboxylate structure. The concentration of Nd(III) in a spent nuclear fuel sample was determined with no interference from various matrix elements, including lanthanides and uranium (at a 200-fold excess), with 92 ± 3% recovery. This is due to high resolution based on establishing a ternary complex equilibrium during migration in which the hydroxyl ion plays an auxiliary role (log KLn-L-OH = 3.9-5.3).

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KW - Capillary electrophoresis

KW - Fluorescence detection

KW - High-level radioactive wastes

KW - Neodymium

KW - Polyaminocarboxylate

KW - Spent nuclear fuel

KW - Ternary complex formation

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Application of capillary electrophoresis with laser-induced fluorescence detection for the determination of trace neodymium in spent nuclear fuel using complexation with an emissive macrocyclic polyaminocarboxylate probe

Abstract

Keywords

ASJC Scopus subject areas

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