(+)-Apollineanin: A new flavanone from Tephrosia apollinea

A. Hisham; Shaly John; Wafa Al-Shuaily; Teigo Asai; Yoshinori Fujimoto

doi:10.1080/14786410500399714

(+)-Apollineanin: A new flavanone from Tephrosia apollinea

A. Hisham, Shaly John, Wafa Al-Shuaily, Teigo Asai, Yoshinori Fujimoto

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Chemical investigation of the leaves of Tephrosia apollinea has yielded a new flavanone named (+)-apollineanin, together with two known flavones: (-)-semiglabrin and (-)-semiglabrinol. The structure of the new compound was determined on the basis of mass, 1D and 2D NMR spectroscopies including NOE difference spectroscopy. The absolute stereochemistry of (+)-apollineanin was determined by Mosher ester methodology and from CD data.

Original language	English
Pages (from-to)	1046-1052
Number of pages	7
Journal	Natural Product Research
Volume	20
Issue number	12
DOIs	https://doi.org/10.1080/14786410500399714
Publication status	Published - 2006 Oct
Externally published	Yes

Keywords

(+)-Apollineanin
(-)-Semiglabrin
(-)-Semiglabrinol
Leguminosae
Tephrosia apollinea

ASJC Scopus subject areas

Analytical Chemistry
Biochemistry
Plant Science
Organic Chemistry

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10.1080/14786410500399714

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title = "(+)-Apollineanin: A new flavanone from Tephrosia apollinea",

abstract = "Chemical investigation of the leaves of Tephrosia apollinea has yielded a new flavanone named (+)-apollineanin, together with two known flavones: (-)-semiglabrin and (-)-semiglabrinol. The structure of the new compound was determined on the basis of mass, 1D and 2D NMR spectroscopies including NOE difference spectroscopy. The absolute stereochemistry of (+)-apollineanin was determined by Mosher ester methodology and from CD data.",

keywords = "(+)-Apollineanin, (-)-Semiglabrin, (-)-Semiglabrinol, Leguminosae, Tephrosia apollinea",

author = "A. Hisham and Shaly John and Wafa Al-Shuaily and Teigo Asai and Yoshinori Fujimoto",

note = "Funding Information: Financial support for this study under SQU grant no. (IG/SCI/CHEM/01/03) is gratefully acknowledged.",

year = "2006",

month = oct,

doi = "10.1080/14786410500399714",

language = "English",

volume = "20",

pages = "1046--1052",

journal = "Natural Product Research",

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TY - JOUR

T1 - (+)-Apollineanin

T2 - A new flavanone from Tephrosia apollinea

AU - Hisham, A.

AU - John, Shaly

AU - Al-Shuaily, Wafa

AU - Asai, Teigo

AU - Fujimoto, Yoshinori

N1 - Funding Information: Financial support for this study under SQU grant no. (IG/SCI/CHEM/01/03) is gratefully acknowledged.

PY - 2006/10

Y1 - 2006/10

N2 - Chemical investigation of the leaves of Tephrosia apollinea has yielded a new flavanone named (+)-apollineanin, together with two known flavones: (-)-semiglabrin and (-)-semiglabrinol. The structure of the new compound was determined on the basis of mass, 1D and 2D NMR spectroscopies including NOE difference spectroscopy. The absolute stereochemistry of (+)-apollineanin was determined by Mosher ester methodology and from CD data.

AB - Chemical investigation of the leaves of Tephrosia apollinea has yielded a new flavanone named (+)-apollineanin, together with two known flavones: (-)-semiglabrin and (-)-semiglabrinol. The structure of the new compound was determined on the basis of mass, 1D and 2D NMR spectroscopies including NOE difference spectroscopy. The absolute stereochemistry of (+)-apollineanin was determined by Mosher ester methodology and from CD data.

KW - (+)-Apollineanin

KW - (-)-Semiglabrin

KW - (-)-Semiglabrinol

KW - Leguminosae

KW - Tephrosia apollinea

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DO - 10.1080/14786410500399714

M3 - Article

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AN - SCOPUS:37849188529

SN - 1478-6419

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JO - Natural Product Research

JF - Natural Product Research

IS - 12

ER -

(+)-Apollineanin: A new flavanone from Tephrosia apollinea

Abstract

Keywords

ASJC Scopus subject areas

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