Anti-[2.2](1,4)phthalocyaninophane: Spectroscopic evidence for transannular interaction in the excited states

Yoshiaki Asano; Atsuya Muranaka; Akira Fukasawa; Terutaka Hatano; Masanobu Uchiyama; Nagao Kobayashi

doi:10.1021/ja068528c

Anti-[2.2](1,4)phthalocyaninophane: Spectroscopic evidence for transannular interaction in the excited states

Yoshiaki Asano, Atsuya Muranaka, Akira Fukasawa, Terutaka Hatano, Masanobu Uchiyama, Nagao Kobayashi

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The design and synthesis of a novel type of bisphthalocyanines, anti-[2.2](1,4)phthalocyaninophanes, were reported. The phthalocyanine dimer exhibited significantly split and red-shifted absorption in the near-IR region and maintained the fluorescence properties of phthalocyanines. The origin of the electronic communication between the two phthalocyanines was rationalized on the basis of the MO model analysis.

Original language	English
Pages (from-to)	4516-4517
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	15
DOIs	https://doi.org/10.1021/ja068528c
Publication status	Published - 2007 Apr 18

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja068528c

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Anti-[2.2](1,4)phthalocyaninophane : Spectroscopic evidence for transannular interaction in the excited states. / Asano, Yoshiaki; Muranaka, Atsuya; Fukasawa, Akira; Hatano, Terutaka; Uchiyama, Masanobu; Kobayashi, Nagao.

In: Journal of the American Chemical Society, Vol. 129, No. 15, 18.04.2007, p. 4516-4517.

Research output: Contribution to journal › Article › peer-review

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Anti-[2.2](1,4)phthalocyaninophane: Spectroscopic evidence for transannular interaction in the excited states

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