Abstract
The design and synthesis of a novel type of bisphthalocyanines, anti-[2.2](1,4)phthalocyaninophanes, were reported. The phthalocyanine dimer exhibited significantly split and red-shifted absorption in the near-IR region and maintained the fluorescence properties of phthalocyanines. The origin of the electronic communication between the two phthalocyanines was rationalized on the basis of the MO model analysis.
| Original language | English |
|---|---|
| Pages (from-to) | 4516-4517 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 129 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - 2007 Apr 18 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Asano, Y., Muranaka, A., Fukasawa, A., Hatano, T., Uchiyama, M., & Kobayashi, N. (2007). Anti-[2.2](1,4)phthalocyaninophane: Spectroscopic evidence for transannular interaction in the excited states. Journal of the American Chemical Society, 129(15), 4516-4517. https://doi.org/10.1021/ja068528c