Anti-[2.2](1,4)phthalocyaninophane: Spectroscopic evidence for transannular interaction in the excited states

Yoshiaki Asano, Atsuya Muranaka, Akira Fukasawa, Terutaka Hatano, Masanobu Uchiyama, Nagao Kobayashi

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

The design and synthesis of a novel type of bisphthalocyanines, anti-[2.2](1,4)phthalocyaninophanes, were reported. The phthalocyanine dimer exhibited significantly split and red-shifted absorption in the near-IR region and maintained the fluorescence properties of phthalocyanines. The origin of the electronic communication between the two phthalocyanines was rationalized on the basis of the MO model analysis.

Original languageEnglish
Pages (from-to)4516-4517
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number15
DOIs
Publication statusPublished - 2007 Apr 18

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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