Anthryl-substituted trialkyldisilene showing distinct intramolecular charge-transfer transition

Takeaki Iwamoto, Maiko Kobayashi, Kei Uchiyama, Shin Sasaki, Selvarajan Nagendran, Hiroyuki Isobe, Mitsuo Kira

Research output: Contribution to journalArticlepeer-review

65 Citations (Scopus)

Abstract

1-Naphthyl-, 9-phenanthryl-, and 9-anthryl-substituted trialkyldisilenes 1-3 were synthesized as the first stable disilenes with single polycyclic aromatic substituents, allowing elucidation of the unprecedented intramolecular charge transfer interaction between disilene π and aromatic π systems. Anthryl-substituted disilene 3 having a low-lying π*LUMO showed a distinct ICT absorption band due to the charge transfer from a disilene π donor to an aromatic π acceptor.

Original languageEnglish
Pages (from-to)3156-3157
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number9
DOIs
Publication statusPublished - 2009 Mar 11

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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