Anomalous role of molecular sieves 4A in the preparation of a binaphthol-derived active μ3-oxo titanium catalyst

Masahiro Terada, Yousuke Matsumoto, Yoshiyuki Nakamura, Koichi Mikami

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

The active species of binaphthol-derived titanium catalyst 1, which is used as an efficient catalyst for glyoxylate-ene reactions, is primarily composed of a μ3-oxo (Ti3O) species, for which the molecular sieves 4A employed in the catalyst preparation act as a H2O donor.

Original languageEnglish
Pages (from-to)281-282
Number of pages2
JournalChemical Communications
Issue number3
DOIs
Publication statusPublished - 1997 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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