Anisotropic free-electron-like dispersions and standing waves realized in self-assembled monolayers of glycine on Cu(100)

Ken Kanazawa, Yasuyuki Sainoo, Yasuaki Konishi, Shoji Yoshida, Atsushi Taninaka, Arifumi Okada, Maxime Berthe, Nobuhiko Kobayashi, Osamu Takeuchi, Hidemi Shigekawa

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

Standing waves (SW), the long-range modulation of local density of states, were observed for the first time in the self-assembled monolayers of an organic molecule. Self-organization of glycine molecules is driven by the interaction based on the chirality and polarity the molecules acquire on a Cu surface. For the structure with a p(2 × 4) periodicity, anisotropic dispersion relations of the 2D electronic state, with the effective masses of 6.1 × 10-2 and 6.1 × 10-1 me, were obtained by analyzing the SW using scanning tunneling microscopy.

Original languageEnglish
Pages (from-to)740-741
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number4
DOIs
Publication statusPublished - 2007 Jan 31
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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    Kanazawa, K., Sainoo, Y., Konishi, Y., Yoshida, S., Taninaka, A., Okada, A., Berthe, M., Kobayashi, N., Takeuchi, O., & Shigekawa, H. (2007). Anisotropic free-electron-like dispersions and standing waves realized in self-assembled monolayers of glycine on Cu(100). Journal of the American Chemical Society, 129(4), 740-741. https://doi.org/10.1021/ja066318u