Anisotropic fragmentation of CF4 following F 1s photoabsorption

Y. Muramatsu; Kiyoshi Ueda; Y. Shimizu; H. Chiba; K. Amano; Y. Sato; H. Nakamatsu

doi:10.1088/0953-4075/32/9/104

Anisotropic fragmentation of CF₄ following F 1s photoabsorption

Y. Muramatsu, Kiyoshi Ueda, Y. Shimizu, H. Chiba, K. Amano, Y. Sato, H. Nakamatsu

Division of Measurements

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

We have investigated the F 1s photoabsorption of a T_d symmetry molecule CF₄ using angle-resolved ion-yield spectroscopy and found that the ionic fragmentation is anisotropic. With the help of first-principles calculations for the symmetry-resolved F 1s absorption spectrum, the anisotropic fragmentation is interpreted as preferential bond rupture at the F 1s core hole site due to symmetry breaking, in contrast to the case for C 1s photoabsorption.

Original language	English
Journal	Journal of Physics B: Atomic, Molecular and Optical Physics
Volume	32
Issue number	9
DOIs	https://doi.org/10.1088/0953-4075/32/9/104
Publication status	Published - 1999 May 14

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Condensed Matter Physics

Access to Document

10.1088/0953-4075/32/9/104

Fingerprint Dive into the research topics of 'Anisotropic fragmentation of CF<sub>4</sub> following F 1s photoabsorption'. Together they form a unique fingerprint.

Cite this

Muramatsu, Y., Ueda, K., Shimizu, Y., Chiba, H., Amano, K., Sato, Y., & Nakamatsu, H. (1999). Anisotropic fragmentation of CF₄ following F 1s photoabsorption. Journal of Physics B: Atomic, Molecular and Optical Physics, 32(9). https://doi.org/10.1088/0953-4075/32/9/104

@article{4ed8e388b1e24b5fb6cf416542ae61e4,

title = "Anisotropic fragmentation of CF4 following F 1s photoabsorption",

abstract = "We have investigated the F 1s photoabsorption of a Td symmetry molecule CF4 using angle-resolved ion-yield spectroscopy and found that the ionic fragmentation is anisotropic. With the help of first-principles calculations for the symmetry-resolved F 1s absorption spectrum, the anisotropic fragmentation is interpreted as preferential bond rupture at the F 1s core hole site due to symmetry breaking, in contrast to the case for C 1s photoabsorption.",

author = "Y. Muramatsu and Kiyoshi Ueda and Y. Shimizu and H. Chiba and K. Amano and Y. Sato and H. Nakamatsu",

year = "1999",

month = may,

day = "14",

doi = "10.1088/0953-4075/32/9/104",

language = "English",

volume = "32",

journal = "Journal of Physics B: Atomic, Molecular and Optical Physics",

issn = "0953-4075",

publisher = "IOP Publishing Ltd.",

number = "9",

}

TY - JOUR

T1 - Anisotropic fragmentation of CF4 following F 1s photoabsorption

AU - Muramatsu, Y.

AU - Ueda, Kiyoshi

AU - Shimizu, Y.

AU - Chiba, H.

AU - Amano, K.

AU - Sato, Y.

AU - Nakamatsu, H.

PY - 1999/5/14

Y1 - 1999/5/14

N2 - We have investigated the F 1s photoabsorption of a Td symmetry molecule CF4 using angle-resolved ion-yield spectroscopy and found that the ionic fragmentation is anisotropic. With the help of first-principles calculations for the symmetry-resolved F 1s absorption spectrum, the anisotropic fragmentation is interpreted as preferential bond rupture at the F 1s core hole site due to symmetry breaking, in contrast to the case for C 1s photoabsorption.

AB - We have investigated the F 1s photoabsorption of a Td symmetry molecule CF4 using angle-resolved ion-yield spectroscopy and found that the ionic fragmentation is anisotropic. With the help of first-principles calculations for the symmetry-resolved F 1s absorption spectrum, the anisotropic fragmentation is interpreted as preferential bond rupture at the F 1s core hole site due to symmetry breaking, in contrast to the case for C 1s photoabsorption.

UR - http://www.scopus.com/inward/record.url?scp=0032680740&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032680740&partnerID=8YFLogxK

U2 - 10.1088/0953-4075/32/9/104

DO - 10.1088/0953-4075/32/9/104

M3 - Article

AN - SCOPUS:0032680740

VL - 32

JO - Journal of Physics B: Atomic, Molecular and Optical Physics

JF - Journal of Physics B: Atomic, Molecular and Optical Physics

SN - 0953-4075

IS - 9

ER -