Anisotropic fragmentation of CF4 following F 1s photoabsorption

Y. Muramatsu, Kiyoshi Ueda, Y. Shimizu, H. Chiba, K. Amano, Y. Sato, H. Nakamatsu

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We have investigated the F 1s photoabsorption of a Td symmetry molecule CF4 using angle-resolved ion-yield spectroscopy and found that the ionic fragmentation is anisotropic. With the help of first-principles calculations for the symmetry-resolved F 1s absorption spectrum, the anisotropic fragmentation is interpreted as preferential bond rupture at the F 1s core hole site due to symmetry breaking, in contrast to the case for C 1s photoabsorption.

Original languageEnglish
JournalJournal of Physics B: Atomic, Molecular and Optical Physics
Volume32
Issue number9
DOIs
Publication statusPublished - 1999 May 14

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics

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