Anionic fluoro complex of element 105, Db

Yoshitaka Kasamatsu; Atsushi Toyoshima; Masato Asai; Kazuaki Tsukada; Zijie Li; Yasuo Ishii; Hayato Tourne; Tetsuya K. Sato; Takahiro Kikuchi; Ichiro Nishinaka; Yuichiro Nagame; Hiromitsu Haba; Hidetoshi Kikunaga; Yuki Kudou; Yasuji Oura; Kazuhiko Akiyama; Wataru Sato; Kazuhiro Ooe; Hiroyuki Fujisawa; Atsushi Shinohara; Shin Ichi Goto; Taichi Hasegawa; Hisaaki Kudo; Tomohiro Nanri; Mikio Araki; Norikazu Kinoshita; Akihiko Yokoyama; Gli Fan; Zhi Qin; Christoph E. Düllmann; Matthias Schädel; Jens V. Kratz

doi:10.1246/cl.2009.1084

Anionic fluoro complex of element 105, Db

Yoshitaka Kasamatsu, Atsushi Toyoshima, Masato Asai, Kazuaki Tsukada, Zijie Li, Yasuo Ishii, Hayato Tourne, Tetsuya K. Sato, Takahiro Kikuchi, Ichiro Nishinaka, Yuichiro Nagame, Hiromitsu Haba, Hidetoshi Kikunaga, Yuki Kudou, Yasuji Oura, Kazuhiko Akiyama, Wataru Sato, Kazuhiro Ooe, Hiroyuki Fujisawa, Atsushi ShinoharaShin Ichi Goto, Taichi Hasegawa, Hisaaki Kudo, Tomohiro Nanri, Mikio Araki, Norikazu Kinoshita, Akihiko Yokoyama, Gli Fan, Zhi Qin, Christoph E. Düllmann, Matthias Schädel, Jens V. Kratz

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

We report on the characteristic anion-exchange behavior of the superheavy element dubnium (Db) with atomic number Z = 105 in HF/HNO ₃ solution at the fluoride ion concentration [F ^-] = 0.003 M. The result clearly demonstrates that the fluoro complex formation of Db is significantly different from that of the group-5 homologue Ta in the 6th period of the periodic table while the behavior of Db is similar to that of the lighter homologue Nb in the 5th period.

Original language	English
Pages (from-to)	1084-1085
Number of pages	2
Journal	Chemistry Letters
Volume	38
Issue number	11
DOIs	https://doi.org/10.1246/cl.2009.1084
Publication status	Published - 2009
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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Kasamatsu, Y., Toyoshima, A., Asai, M., Tsukada, K., Li, Z., Ishii, Y., Tourne, H., Sato, T. K., Kikuchi, T., Nishinaka, I., Nagame, Y., Haba, H., Kikunaga, H., Kudou, Y., Oura, Y., Akiyama, K., Sato, W., Ooe, K., Fujisawa, H., ... Kratz, J. V. (2009). Anionic fluoro complex of element 105, Db. Chemistry Letters, 38(11), 1084-1085. https://doi.org/10.1246/cl.2009.1084

Kasamatsu, Y, Toyoshima, A, Asai, M, Tsukada, K, Li, Z, Ishii, Y, Tourne, H, Sato, TK, Kikuchi, T, Nishinaka, I, Nagame, Y, Haba, H, Kikunaga, H, Kudou, Y, Oura, Y, Akiyama, K, Sato, W, Ooe, K, Fujisawa, H, Shinohara, A, Goto, SI, Hasegawa, T, Kudo, H, Nanri, T, Araki, M, Kinoshita, N, Yokoyama, A, Fan, G, Qin, Z, Düllmann, CE, Schädel, M & Kratz, JV 2009, 'Anionic fluoro complex of element 105, Db', Chemistry Letters, vol. 38, no. 11, pp. 1084-1085. https://doi.org/10.1246/cl.2009.1084

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title = "Anionic fluoro complex of element 105, Db",

abstract = "We report on the characteristic anion-exchange behavior of the superheavy element dubnium (Db) with atomic number Z = 105 in HF/HNO 3 solution at the fluoride ion concentration [F -] = 0.003 M. The result clearly demonstrates that the fluoro complex formation of Db is significantly different from that of the group-5 homologue Ta in the 6th period of the periodic table while the behavior of Db is similar to that of the lighter homologue Nb in the 5th period.",

author = "Yoshitaka Kasamatsu and Atsushi Toyoshima and Masato Asai and Kazuaki Tsukada and Zijie Li and Yasuo Ishii and Hayato Tourne and Sato, {Tetsuya K.} and Takahiro Kikuchi and Ichiro Nishinaka and Yuichiro Nagame and Hiromitsu Haba and Hidetoshi Kikunaga and Yuki Kudou and Yasuji Oura and Kazuhiko Akiyama and Wataru Sato and Kazuhiro Ooe and Hiroyuki Fujisawa and Atsushi Shinohara and Goto, {Shin Ichi} and Taichi Hasegawa and Hisaaki Kudo and Tomohiro Nanri and Mikio Araki and Norikazu Kinoshita and Akihiko Yokoyama and Gli Fan and Zhi Qin and D{\"u}llmann, {Christoph E.} and Matthias Sch{\"a}del and Kratz, {Jens V.}",

year = "2009",

doi = "10.1246/cl.2009.1084",

language = "English",

volume = "38",

pages = "1084--1085",

journal = "Chemistry Letters",

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T1 - Anionic fluoro complex of element 105, Db

AU - Kasamatsu, Yoshitaka

AU - Toyoshima, Atsushi

AU - Asai, Masato

AU - Tsukada, Kazuaki

AU - Li, Zijie

AU - Ishii, Yasuo

AU - Tourne, Hayato

AU - Sato, Tetsuya K.

AU - Kikuchi, Takahiro

AU - Nishinaka, Ichiro

AU - Nagame, Yuichiro

AU - Haba, Hiromitsu

AU - Kikunaga, Hidetoshi

AU - Kudou, Yuki

AU - Oura, Yasuji

AU - Akiyama, Kazuhiko

AU - Sato, Wataru

AU - Ooe, Kazuhiro

AU - Fujisawa, Hiroyuki

AU - Shinohara, Atsushi

AU - Goto, Shin Ichi

AU - Hasegawa, Taichi

AU - Kudo, Hisaaki

AU - Nanri, Tomohiro

AU - Araki, Mikio

AU - Kinoshita, Norikazu

AU - Yokoyama, Akihiko

AU - Fan, Gli

AU - Qin, Zhi

AU - Düllmann, Christoph E.

AU - Schädel, Matthias

AU - Kratz, Jens V.

PY - 2009

Y1 - 2009

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AB - We report on the characteristic anion-exchange behavior of the superheavy element dubnium (Db) with atomic number Z = 105 in HF/HNO 3 solution at the fluoride ion concentration [F -] = 0.003 M. The result clearly demonstrates that the fluoro complex formation of Db is significantly different from that of the group-5 homologue Ta in the 6th period of the periodic table while the behavior of Db is similar to that of the lighter homologue Nb in the 5th period.

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VL - 38

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EP - 1085

JO - Chemistry Letters

JF - Chemistry Letters

IS - 11

ER -

Anionic fluoro complex of element 105, Db

Abstract

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