Anion Recognition at the Solid/Liquid Interface as Studied by Second Harmonic Generation Spectroscopy

Akira Yamaguchi; Ryo Kato; Seiichi Nishizawa; Norio Teramae

doi:10.1246/cl.2003.798

Anion Recognition at the Solid/Liquid Interface as Studied by Second Harmonic Generation Spectroscopy

Akira Yamaguchi, Ryo Kato, Seiichi Nishizawa, Norio Teramae

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A self-assembled monolayer of thiourea-based anion receptor was formed at a gold surface, and its affinity with monovalent inorganic anions (MeCO ₂^-, H₂PO₄^-, Cl ^-) in acetonitrile solution was examined by second harmonic generation spectroscopy. The estimated adsorption coefficients of anions at the monolayer reveal specific binding selectivity compared with the selectivity found in a bulk acetonitrile phase.

Original language	English
Pages (from-to)	798-799
Number of pages	2
Journal	Chemistry Letters
Volume	32
Issue number	9
DOIs	https://doi.org/10.1246/cl.2003.798
Publication status	Published - 2003 Sept 5

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2003.798

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abstract = "A self-assembled monolayer of thiourea-based anion receptor was formed at a gold surface, and its affinity with monovalent inorganic anions (MeCO 2-, H2PO4-, Cl -) in acetonitrile solution was examined by second harmonic generation spectroscopy. The estimated adsorption coefficients of anions at the monolayer reveal specific binding selectivity compared with the selectivity found in a bulk acetonitrile phase.",

author = "Akira Yamaguchi and Ryo Kato and Seiichi Nishizawa and Norio Teramae",

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AU - Teramae, Norio

PY - 2003/9/5

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N2 - A self-assembled monolayer of thiourea-based anion receptor was formed at a gold surface, and its affinity with monovalent inorganic anions (MeCO 2-, H2PO4-, Cl -) in acetonitrile solution was examined by second harmonic generation spectroscopy. The estimated adsorption coefficients of anions at the monolayer reveal specific binding selectivity compared with the selectivity found in a bulk acetonitrile phase.

AB - A self-assembled monolayer of thiourea-based anion receptor was formed at a gold surface, and its affinity with monovalent inorganic anions (MeCO 2-, H2PO4-, Cl -) in acetonitrile solution was examined by second harmonic generation spectroscopy. The estimated adsorption coefficients of anions at the monolayer reveal specific binding selectivity compared with the selectivity found in a bulk acetonitrile phase.

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Anion Recognition at the Solid/Liquid Interface as Studied by Second Harmonic Generation Spectroscopy

Abstract

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