An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

Atsutoshi Yokoyama; Jung Eun Han; Kenneth D. Karlin; Wonwoo Nam

doi:10.1039/c3cc48782b

An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

Atsutoshi Yokoyama, Jung Eun Han, Kenneth D. Karlin, Wonwoo Nam

Research output: Contribution to journal › Article

16 Citations (Scopus)

Abstract

Reaction of a nonheme iron(III)-peroxo complex, [Fe^III(14-TMC)(O₂)]⁺, with NO⁺, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O₂ = ⁻) + NO], affords an iron(IV)-oxo complex, [Fe^IV(14-TMC)(O)]²⁺, and nitrogen dioxide (NO₂), followed by conversion to an iron(III)-nitrato complex, [Fe^III(14-TMC)(NO₃)(F)]⁺. 2014

Original language	English
Pages (from-to)	1742-1744
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	14
DOIs	https://doi.org/10.1039/c3cc48782b
Publication status	Published - 2014 Jan 21

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Yokoyama, A., Han, J. E., Karlin, K. D., & Nam, W. (2014). An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion. Chemical Communications, 50(14), 1742-1744. https://doi.org/10.1039/c3cc48782b

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abstract = "Reaction of a nonheme iron(III)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2 = −) + NO], affords an iron(IV)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [FeIII(14-TMC)(NO3)(F)]+. 2014",

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AB - Reaction of a nonheme iron(III)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2 = −) + NO], affords an iron(IV)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [FeIII(14-TMC)(NO3)(F)]+. 2014

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