An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

Atsutoshi Yokoyama, Jung Eun Han, Kenneth D. Karlin, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

21 Citations (Scopus)

Abstract

Reaction of a nonheme iron(III)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2 = ) + NO], affords an iron(IV)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [FeIII(14-TMC)(NO3)(F)]+. 2014

Original languageEnglish
Pages (from-to)1742-1744
Number of pages3
JournalChemical Communications
Volume50
Issue number14
DOIs
Publication statusPublished - 2014 Jan 21
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion'. Together they form a unique fingerprint.

Cite this