An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

Atsutoshi Yokoyama, Jung Eun Han, Kenneth D. Karlin, Wonwoo Nam

    Research output: Contribution to journalArticle

    16 Citations (Scopus)

    Abstract

    Reaction of a nonheme iron(III)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2 = ) + NO], affords an iron(IV)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [FeIII(14-TMC)(NO3)(F)]+. 2014

    Original languageEnglish
    Pages (from-to)1742-1744
    Number of pages3
    JournalChemical Communications
    Volume50
    Issue number14
    DOIs
    Publication statusPublished - 2014 Jan 21

    ASJC Scopus subject areas

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

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