An ionicity diagram for the family of [{Ru 2(CF 3CO 2) 4} 2(TCNQR x)] (TCNQR x = R-substituted 7,7,8,8-tetracyano-p-quinodimethane)

Keita Nakabayashi, Masaki Nishio, Keiko Kubo, Wataru Kosaka, Hitoshi Miyasaka

Research output: Contribution to journalArticlepeer-review

37 Citations (Scopus)

Abstract

A diagram of energies between the HOMO of donor (D) and LUMO of acceptor (A) vs. ΔE 1/2(DA) (= E 1/2(D) - E 1/2(A): E 1/2 = first-redox potential) clearly demonstrates the ionicity in the series of D/A assemblies, [{Ru 2(CF 3CO 2) 4} 2(TCNQR x)]·n(solv) (TCNQR x = 2,5- or 2,3,5,6-R-substituted 7,7,8,8-tetracyano-p- quinodimethane; R x = H 4, F 2, Cl 2, Br 2, F 4, Me 2, (OMe) 2).

Original languageEnglish
Pages (from-to)6072-6074
Number of pages3
JournalDalton Transactions
Volume41
Issue number20
DOIs
Publication statusPublished - 2012 May 28
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry

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