An Extremely Air-Stable 19π Porphyrinoid

Takuya Yoshida, Wen Zhou, Taniyuki Furuyama, Daniel B. Leznoff, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)

Abstract

A one-electron reduced species of a cationic phosphorus(V) tetraazaporphyrin complex has been isolated as an air-stable solid. Cyclic voltammetry and magnetic measurements showed the species to be a neutral π radical, and the solid state structure was elucidated by single crystal X-ray diffraction analysis. Magnetic circular dichroism spectroscopy and theoretical calculations also support a 19π electron conjugated electronic circuit.

Original languageEnglish
Pages (from-to)9258-9261
Number of pages4
JournalJournal of the American Chemical Society
Volume137
Issue number29
DOIs
Publication statusPublished - 2015 Jul 29

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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